Why is it important that we have defined the system as the dissolved ions and their respective solvation shells?

Introductory Chemistry: An Active Learning Approach
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Author:Mark S. Cracolice, Ed Peters
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Chapter16: Solutions
Section: Chapter Questions
Problem 130E: When 19.77g of glucose, C6H12O6(180.2g/mol), is dissolved in 225.6g of an organic solvent, the...
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Why is it important that we have defined the system as the dissolved ions and their respective solvation shells? 

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