Why is the photodissociation of oxygen more important than the photoionization of oxygen at altitudes below about 90 km

Principles of Modern Chemistry
8th Edition
ISBN:9781305079113
Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Chapter20: Molecular Spectroscopy And Photochemistry
Section: Chapter Questions
Problem 49P
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7.) Why is the photodissociation of oxygen more important than the photoionization of oxygen at altitudes below about 90 km.

A) because the pressure is higher
B) because of the higher temperature
C) because all of the lower energy photons required for photoionization have already been absorbed
D) because all of the higher energy photons required for photoionization have already been absorbed
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