Write a flow diagram Prepare a written copy of the complete separation scheme for a solution that contains Ag+, Fe3+, Cr3+, Ni2+, Zn2+, and Ba2+. Make sure that your separation scheme includes:separation of each ion into its own individual sample AND precipitation BEFORE a confirmation test is doneall phases and visible colors, if applicablereagents and conditions necessary to carry out each stepbalanced equations, including phases, for each step Data for the preliminary tests for each metal are included below. If a precipitate wasformed, the color was noted. Precipitates that dissolved were also noted. If no data isincluded, the ion did not precipitate.Ag*Fe3+Cr3*Ni2+Zn2+REAGENTSTest 13.0М HаBa2+White pptTest 21.0 M NH3 White ppt Brown ppt White ppt White ppt White ppt White pptuntil basic15 M NH3in excessTest 33.0/6.0 MNaOH untildissolvedDissolved dissolvedWhite ppt Red ppt White ppt White ppt White pptbasic6 M NAOHin excessdissolveddissolved White pptTest 43.0 MWhite pptH2SO4

Write a flow diagram Prepare a written copy of the complete separation scheme for a solution that contains Ag+, Fe3+, Cr3+, Ni2+, Zn2+, and Ba2+. Make sure that your separation scheme includes: separation of each ion into its own individual sample AND precipitation BEFORE a confirmation test is done all phases and visible colors, if applicable reagents and conditions necessary to carry out each step balanced equations, including phases, for each step

Write a flow diagram Prepare a written copy of the complete separation scheme for a solution that contains Ag+, Fe3+, Cr3+, Ni2+, Zn2+, and Ba2+. Make sure that your separation scheme includes: separation of each ion into its own individual sample AND precipitation BEFORE a confirmation test is done all phases and visible colors, if applicable reagents and conditions necessary to carry out each step balanced equations, including phases, for each step

Chemical Principles in the Laboratory

11th Edition

ISBN:9781305264434

Author:Emil Slowinski, Wayne C. Wolsey, Robert Rossi

Publisher:Emil Slowinski, Wayne C. Wolsey, Robert Rossi

Chapter27: Relative Stabilities Of Complex Ions And Precipitates Prepared From Solutions Of Copper(ii)

Section: Chapter Questions

Problem 1ASA

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A 1.000-g sample containing bromide was dissolved in sufficient water to give 100.0 mL. A 50.00 mL aliquot was measured and after acidification, silver nitrate was introduced to precipitate AgBr, which was filtered, washed, and then dissolved in an ammoniacal solution of potassium tetracyanonickelate(II): Ni(CN)42- + 2AgBr(s) → 2Ag(CN)2- + Ni2+ + 2Br- The liberated nickel ion required 11.70 mL of 0.002146 M EDTA. Calculate mmol Ni in the 50.00 mL aliquot. Calculate mmol Br- in the 50.00 mL aliquot. Calculate the percentage of NaBr (102.894) in the 1.000 g sample.
A 1.000-g sample containing bromide was dissolved in sufficient water to give 100.0 mL. A 50.00 mL aliquot was measured and after acidification, silver nitrate was introduced to precipitate AgBr, which was filtered, washed, and then dissolved in an ammoniacal solution of potassium tetracyanonickelate(II): Ni(CN)42- + 2AgBr(s) → 2Ag(CN)2- + Ni2+ + 2Br- The liberated nickel ion required 11.70 mL of 0.002146 M EDTA The other 50.00 mL remaining solution was also analyzed for its Br- content by potentiometry using a metallic electrode of the second kind. Ecell recorded in running the solution using the potentiometric set-up was Ecell = 0.0286 V. (E0Ag/AgBr = 0.095 V) g) Compute for Eind. h) Compute pBr in the 50.00 mL aliquot. i) Compute for % NaBr ( in the potentiometric technique). j) Calculate the error between the obtained % NaBr fr the EDTA titration technique and the % NaBr from the potentiometric technique.
a. write the net ionic equation involved in the formation of copper complexes in: Reagent added ligand added 1 control - 2 0.5 mL of 12M NH3 NH3 3 5 drops of 5M HCl Cl- b. starting from the copper (ii) complexes in the table above, write the net ionic equation involved in the ligand substitution reactions as observed in: Reagent added reagent added 1a 0.25 mL of 12 MNH3 1b 0.22g of KCl 2a 0.25 mL H2O 2b 0.22g of KCl 3a 0.25 mL H2O 3b 0.25 mL of 12M NH3
A 1.000-g sample containing bromide was dissolved in sufficient water to give 100.0 mL. A 50.00 mL aliquot was measured and after acidification, silver nitrate was introduced to precipitate AgBr, which was filtered, washed, and then dissolved in an ammoniacal solution of potassium tetracyanonickelate(II): Ni(CN)42- + 2AgBr(s) → 2Ag(CN)2- + Ni2+ + 2Br-50.00 mL remaining solution was analyzed for its Br- content by potentiometry using a metallic electrode of the second kind. a) Write the cell notation of the potentiometric set-up with SCE as the reference electrode. b) Write the Nernst equation that describes the indicator electrode set-up. Ecell recorded in running the solution using the potentiometric set-up was Ecell = 0.0286 V. (E0Ag/AgBr = 0.095 V) c) Compute for Eind. d) Compute pBr in the 50.00 mL aliquot. e) Compute for % NaBr ( in the potentiometric technique).
Scott test is one of the methods used for screening for Cocaine in Forensic Chemistry. The multi step method consists of a) reacting the sample drug with cobaltous thiocyanate b) dissolving of the formed precipitate by adding HCl and c) extraction of coordination compound with Chloroform d) measurement of absorbance of extracted coordination compound at 627 nm What reaction occurs when HCl is added to dissolve the precipitate ? a.Lewis acid- Lewis base reaction b.Lewis acid- Bronsted Lowry base reactionc.Bronsted Lowry acid – Bronsted Lowry base reaction d.Arrhenius acid – Arrhenius base reaction
Chromel is an alloy composed of nickel, iron and chromium.A 0.6472 g sample was dissolved and diluted to 250 mL. When a50 mL aliquot of 0.05182 M EDTA was mixed with an equal volumeof the diluted sample and all the three ions were chelated, a 5.11 mLback titration with 0.06241 M copper (II) was required.The chromium in a second 50 mL aliquot was masked through theaddition of hexamethylenetetramine, titration of the Fe and Nirequired 36.28 mL of 0.05182 M EDTA.Iron and chromium were masked with pyrophosphate in a third50 mL aliquot and the nickel was titrated with 25.91 mL of theEDTA solution.Calculate the percentage of nickel, chromium and iron in thealloy.
A 1.000-g sample containing bromide was dissolved in sufficient water to give 100.0 mL. A 50.00 mL aliquot was measured and after acidification, silver nitrate was introduced to precipitate AgBr, which was filtered, washed, and then dissolved in an ammoniacal solution of potassium tetracyanonickelate(II): Ni(CN)42- + 2AgBr(s) → 2Ag(CN)2- + Ni2+ + 2Br-Nickel ion required 11.70 mL of 0.002146 M EDTAWhat is the percentage of NaBr (102.894) in the 1.000 g sample?
This is the lab with my data sheet and please answer all of them. Thank you and please answer all of them. If you do it would be appreciated My data to support answers for questions. The equilibrium is Fe3+ + SCN- <--> [FeSCN]2+. The Fe3+ is a pale yellow colour and the complex ion product is red.Stresses:Add KSCN - turned deep redAdd Fe(NO3)3 - turned deep redAdd Na2CO3 - turned yellow/colourlessAdd NaOH - turned yellow/colourlessAdd NH3 - turned yellow/colourlessHeat - turned lighter orange colourCold - turned darker orange colour Addition of NH3(aq) to test tube #6: As a result of the colour change, what can be concluded about the [FeSCN2+(aq)]? Explain. Explain why the addition of NH3(aq) affects the [FeSCN2+(aq)] as indicated in (a). Use chemical reaction in your explanation. Addition of heat/cold to test tube #7 & 8: As a result of the colour change, what can be concluded about the [FeSCN2+(aq)] when the temperature is increased? Explain. As a result of the colour…
This is the lab with my data sheet and please answer all of them. Thank you and please answer all of them. If you do it would be appreciated My data to support answers for questions. The equilibrium is Fe3+ + SCN- <--> [FeSCN]2+. The Fe3+ is a pale yellow colour and the complex ion product is red.Stresses:Add KSCN - turned deep redAdd Fe(NO3)3 - turned deep redAdd Na2CO3 - turned yellow/colourlessAdd NaOH - turned yellow/colourlessAdd NH3 - turned yellow/colourlessHeat - turned lighter orange colourCold - turned darker orange colour Addition of heat/cold to test tube #7 & 8: As a result of the colour change, what can be concluded about the [FeSCN2+(aq)] when the temperature is increased? Explain. As a result of the colour change, what can be concluded about the [FeSCN2+(aq)] when the temperature is decreased? Explain. What can you conclude about the reaction (i.e. is it endothermic or exothermic) based on the above results?
This is the lab with my data sheet and please answer all of them. Thank you and please answer all of them. If you do it would be appreciated My data to support answers for questions. The equilibrium is Fe3+ + SCN- <--> [FeSCN]2+. The Fe3+ is a pale yellow colour and the complex ion product is red.Stresses:Add KSCN - turned deep redAdd Fe(NO3)3 - turned deep redAdd Na2CO3 - turned yellow/colourlessAdd NaOH - turned yellow/colourlessAdd NH3 - turned yellow/colourlessHeat - turned lighter orange colourCold - turned darker orange colour Addition of Na2CO3(s) to test tube #4: d) Explain why the addition of Na2CO3(aq) affects the [FeSCN2+(aq)] as indicated in (a). Use a chemical reaction in your explanation. Addition of NaOH(aq) test tube #5: e) As a result of the colour change, what can be concluded about the [FeSCN2+(aq)]? Explain. f) Explain why the addition of NaOH(aq) affects the [FeSCN2+(aq)] as indicated in (a). Use a chemical reaction in your explanation.
This is the lab with my data sheet and please answer all of them. Thank you and please answer all of them. If you do it would be appreciated My data to support answers for questions. The equilibrium is Fe3+ + SCN- <--> [FeSCN]2+. The Fe3+ is a pale yellow colour and the complex ion product is red.Stresses:Add KSCN - turned deep redAdd Fe(NO3)3 - turned deep redAdd Na2CO3 - turned yellow/colourlessAdd NaOH - turned yellow/colourlessAdd NH3 - turned yellow/colourlessHeat - turned lighter orange colourCold - turned darker orange colour Addition of Fe(NO3)3(aq) to test tube #3: a) what can you infer about the system from the colour change of the solution? b)How can this be possible if no additional SCN-(aq) has been introduced? Addition of Na2CO3(s) to test tube #4: c) As a result of the colour change, what can be concluded about the [FeSCN2+(aq)]? Explain. d) Explain why the addition of Na2CO3(aq) affects the [FeSCN2+(aq)] as indicated in (a). Use a chemical reaction in your…
You are assigned an unknown solution that contains Group III cations. To -1 mL of this solution was added 6 M NH3 the solution was agitated to mix well, and a reddish-brown precipitate with a gelatinous solid clinging to the inner walls of the test tube was observed. The solution was centrifuged and the supernatant was tested for completeness of precipitation by adding an additional drop of 6 M NH3. No cloudiness was observed as the drop of reagent diffused through the solution. The supernatant was then carefully decanted into a clean test tube, labeled (1st solution), and saved for further testing later. The precipitate remaining in the test tube was washed with a small amount of water, centrifuged, and the wash decanted and discarded. To the precipitate was added about 10 drops of 6 M NAOH plus ~1 mL H20 and the test tube was vigorously agitated. The resulting suspension was centrifuged and the supernatant liquid was transferred to another clean test tube and clearly labeled (2nd…