Write down the set of quantum numbers that describe the 4th and 11th electrons of Mg atom. 2. A. В. Write down the orbital diagram for each transition metal ion below, and predict whether the ion is paramagnetic or diamagnetic. (a) Cu'* (Z=29) (b) Zn2* (Z=30) С. Are the following combinations allowed? If not, show two ways to correct them: (a) n = 2; 1= 0; m¡ = -1; ms=+1/2 (b) n = 3; 1= 1; m = 0, mş= -1/2 (c) n = 4; 1= 3; mị = -1; ms= -1/2 (d) n = 3; 1= 3; m = +2; mş=+1/2

Chemistry: An Atoms First Approach
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Chapter20: Transition Metals And Coordination Chemistry
Section: Chapter Questions
Problem 1RQ: What two first-row transition metals have unexpected electron configurations? A statement in the...
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Write down the set of quantum numbers that describe the 4th and 11th electrons of
Mg atom.
2. А.
В.
Write down the orbital diagram for each transition metal ion below, and predict
whether the ion is paramagnetic or diamagnetic.
(a) Cul* (Z=29)
(b) Zn²* (Z=30)
С.
Are the following combinations allowed? If not, show two ways to correct them:
(a) n = 2; 1 = 0; mị = -1; ms= +1/2
(b) n = 3; 1= 1; mị = 0, mş=-1/2
(c) n= 4; 1= 3; mị = -1; ms= -1/2
(d) n = 3; 1= 3; mị = +2; mş=+1/2
In which of the following ground state electron distribution, the Hund's rule is
violated? Justify your answer.
D.
(A)
(B)
(C)
(D)
Е.
Which of the following is a violation of Pauli's exclusion principle? Justify your
answer.
(A) 11
(B) tt
(C) 14
(D) f
Transcribed Image Text:Write down the set of quantum numbers that describe the 4th and 11th electrons of Mg atom. 2. А. В. Write down the orbital diagram for each transition metal ion below, and predict whether the ion is paramagnetic or diamagnetic. (a) Cul* (Z=29) (b) Zn²* (Z=30) С. Are the following combinations allowed? If not, show two ways to correct them: (a) n = 2; 1 = 0; mị = -1; ms= +1/2 (b) n = 3; 1= 1; mị = 0, mş=-1/2 (c) n= 4; 1= 3; mị = -1; ms= -1/2 (d) n = 3; 1= 3; mị = +2; mş=+1/2 In which of the following ground state electron distribution, the Hund's rule is violated? Justify your answer. D. (A) (B) (C) (D) Е. Which of the following is a violation of Pauli's exclusion principle? Justify your answer. (A) 11 (B) tt (C) 14 (D) f
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