Write the overall equation for the process assuming a one electron transfer takes Page 3 It is thought that the reduction of [Fe(phen);+ by [Fe(CN)6]" a. most likely occurs via an outer-sphere mechanism. i. place. ii. Write out, with annotations, the mechanism for the reaction. The redox couples for the half equations below are involved in the terminal respiratory chain. b. FAD + 2H + 2e FADH2 NAD* + 2H* + 2e NADH + H* E" = -0.219 V E" = -0.320 V Write the chemical equation that is most likely to occur between the NAD*|NADH and the FAD FADH redox couples. Hence, calculate the electrode potential of the overall reaction. i. ii. Calculate AG and K for the reaction at 25 °C. The standard reduction potential of the Fe"(aq) Fe (aq) couple is 0.77 V. When ligand L is incorporated in the iron complexes the redox potential becomes 1.02 V. Determine whether ligand L is most likely to с. be classified a T-donor a as or T-acceptor. Give a full account of your reasoning.

Write the overall equation for the process assuming a one electron transfer takes Page 3 It is thought that the reduction of [Fe(phen);+ by [Fe(CN)6]" a. most likely occurs via an outer-sphere mechanism. i. place. ii. Write out, with annotations, the mechanism for the reaction. The redox couples for the half equations below are involved in the terminal respiratory chain. b. FAD + 2H + 2e FADH2 NAD* + 2H* + 2e NADH + H* E" = -0.219 V E" = -0.320 V Write the chemical equation that is most likely to occur between the NAD*|NADH and the FAD FADH redox couples. Hence, calculate the electrode potential of the overall reaction. i. ii. Calculate AG and K for the reaction at 25 °C. The standard reduction potential of the Fe"(aq) Fe (aq) couple is 0.77 V. When ligand L is incorporated in the iron complexes the redox potential becomes 1.02 V. Determine whether ligand L is most likely to с. be classified a T-donor a as or T-acceptor. Give a full account of your reasoning.

Principles of Instrumental Analysis

7th Edition

ISBN:9781305577213

Author:Douglas A. Skoog, F. James Holler, Stanley R. Crouch

Publisher:Douglas A. Skoog, F. James Holler, Stanley R. Crouch

Chapter33: Automated Methods Of Analysis

Section: Chapter Questions

Problem 33.2QAP

See similar textbooks

Similar questions

A 0.1017-g sample of KBrO3 (MW = 167 g/mole) was dissolved in dilute HCl and treated with an unmeasured excess of KI. The liberated iodine required 39.75 mL of a sodium thiosulfate solution. Calculate the molar concentration of the Na2S2O3. BrO3 - + 6I + 6HCl → Br - + 3I2 + 6KCl + 3H2O I2 + Na2S2O3 → 2NaI + Na2S4O6 The type of redox titration reaction is ___. a. iodimetry b. bromination c. iodometry d. diazotination The role of KBrO3 in the titration is ___. a. reducing agent b. oxidizing agent c. source of Br2 d. source of I2 At the endpoint of titration, the equivalence of sodium thiosulfate is equal to the following, EXCEPT ___ . a. equivalence of KI b. equivalence of liberated I2 c. equivalence of KBrO3 d. none of the other choices
What will happen to the estimated vitamin C content of the peach sample if it contains other compounds with reducing property? Explain. https://www.chegg.com/homework-help/questions-and-answers/1-happen-estimated-vitamin-c-content-peach-sample-contains-compounds-reducing-property-exp-q77588726
Briefly explain about Degradation of azo dyes , include aerobic, anaerobic etc.
Using a spectrophotometric technique, the phosphorus content in a mineral will be prolonged. The procedure used is described below: 8.35 g of sample are dissolved and treated so that all phosphorus is converted to the blue orthophosphate complex and made up to volume with distilled water end of 100 ml. The transmission of the resulting solution is 30.6%. If the orthophosphate standard solution of sodium, which is treated in the same way, and which has a final concentration of 2.467x10-4 M, gave a transmittance of 20.5%, calculate the phosphorus content in the driven sample in ppm Na3PO4.
kindly answer this problem and follow this format GIVEN REQUIRED SOLUTION and write regibly thank you so much For the adsorption of a substance A from aqueous solution by charcoal at25oC the freundlich constants are n=3.0 and k=0.50 for y in grams per gramand C in grams per liter. What weight of a W is adsorbed by 2 g of charcoalfrom 1 L of a solution containing originally 2 g of the substance?
Can you please show D and E thank you
a. At pH 4.4, there exists in solution equal amounts of the neutral and charged atropine molecules b. Atropine is a non-electrolyte drug c. Atropine releases its proton at pH 4.4 d. Atropine is most soluble at pH values higher than 4.4 e. If atropine is to be prepared in transdermal patches, the solution in the patch reservoir should have a pH less than 4.4 for maximum absorption.
Calculate the value of the denaturation constant kd for a given enzyme, using the equation provided from the text and lecture of kd = Ad e(-Ed/RT) where Ad = 6.1 x 1047 and Ed = 69 kcal/g mole. Then, prepare a plot of per cent enzyme maximal activity vs temperature using an Ea of 23 kcal/gmole, and an enzyme concentration E0 of unity. Note that the y-axis of this plot is a per cent value, so the value of A in the Arrhenius equation does not need to be known in this case. On the denaturation side of the curve, use 5 minutes as the constant exposure time. Use a temperature range of 20 to 50⁰C.
What are the consequences if an EDTA tube is filled first before a red top tube?
Give TYPED answer only asap
if possible please post links used for summary a. Summarize and briefly explain the chemical interaction between EDC and NHS in Electrochemical Biosensing (CHEMICAL NAME: N-ethyl-N′-(3-(dimethylamino)propyl)carbodiimide/N-hydroxysuccinimide) b. Summarize and briefly explain the chemical interaction between Biotin & Avidin in Electrochemical Biosensing
Please write and show the balanced chemical reactions (on the upper part (above letter A) and under determination of the concentration EDTA solution). Hint: Experimental Procedure: A. Preparation of 0.01M EDTA solution Transfer about 2-g of disodium dihydrogen EDTA dihydrate and 0.1-g of MgCl2•6H2O into a clean 400-mL beaker and dissolve the solids in water. If the solution appears turbid, add NaOH solution until the solution is clear. Transfer the solution into an amber bottle, add enough distilled water to make about 0.500 L and mix thoroughly. Label the contents of the bottle as 0.01 M EDTA. B. Standardization of 0.01M EDTA solution using CaCO3 as Primary Standard You should prepare the Ca2+ standard solution as follows: accurately weigh about 0.2-0.4-g of primary standard CaCO3 that has been previously dried at 100oC. Transfer the solid to a 250-ml volumetric flask, using about 100-mL water. Slowly add 1:1 HCl dropwise until effervescence ceases and the solution is clear.…