Yotate C-C bond Trans both Ō brans to each other Now bothl0) cis to each other act as Tridented not act as tridented ligand Ligand tep 2

Q: lculate IP of Fe when tetradentate ligand above share 4 Ione pairs with Fe?

A:

Q: Rank ligand type from weakest field to strongest field: - pi donor  - sigma only  - pi acceptor

A: Please have a look on the solution:

Q: Why can NH3 serve as a ligand but BH3 cannot?

A:

Q: xplain the complexes below using Ligand Field Theory 1. [RhCl3(OH)3]3- 2. [Cr(en)2(PMe3)2]

A: The electrostatic crystal field theory and the molecular orbital theory were combined into a more…

Q: What is ligan

A: The word ligand comes from the Latin term that means "to bind." A ligand is an ion or molecule that…

Q: Which of the following pairs are coordination isomers? O A. [PtCl4(H2O)2]Cl2 and [PtCl3(H20)2]Cl3 B.…

A:

Q: The weakest trans-effect ligand is

A:

Q: Water is an example of a ________ ligand. a. unidentate b. None of the given choices c. bidentate d.…

A: Water is an example of MONODENTATE ligand.

Q: Association reaction is the only pathway for ligand substitution in a square planar complex because…

A:

Q: complex ECULNH;)ys absorbs hight with a wove 342nm.What is the valye of A in KJ mole ? kngth of

A: CuNH342+ absorbs light with a wavelength of 342 nm .We have to find out the value of ∆° for the…

Q: a) [TiCI(Cp)2(CN)] Oxidation state of metal: X+(-1)+0+(-1)=0 X=+2 Ligand: chloro, cyclopentadiene,…

A: the solution  is as follows:

Q: (a) Explain the hybridization and structure of the following complexes [Cu(NH3)4]SO4 Zn₂[Fe(CN)6]…

A: Given,

Q: Calculate the crystal field stabilizing energy (CFSE) for the complexes below.

A:

Q: Upioad alse (a) Predict whether [Cr(H:O)]" complex is paramagnetic or diamagnetic using VBT. (b)…

A: Diamagnetic substances can be defined as the substances that contain paired electrons and do not…

Q: 38. Which of these species cannot act as a ligand? A CH3NH2 B H2NCH2CH2NH2 C CH.CH,NH2 D CH,NH,

A: Answer - D) CH3 NH3+ Ligand act as electron pair donar to metal to form coordinate bond

Q: A good example of multidentate ligand is a. water. b. ammonia. c. EDTA. d. None of the given…

A: Interpretation: A good example of multidentate ligand is to be determined.

Q: Which statements is incorrect for tetrahedral compounds? Options 4 A, × -A0 Tetrahedral compounds…

A: Correct answer is : Tetrahedral compounds are always low spin complexes. Tetrahedral complexes are…

Q: Draw the geometry of the following a) Triammineaquadichlorocobalt (III) chloride     b)…

A: Since you have posted question with multiple sub-parts, we are entitled to answer the first 3 only.

Q: Calculate the electron in the following complexes. a,b,c,d

A: We have given that  Calculate the electron in the given complexes.

Q: prdination mpound Coordination Magnatic Counter HOMO sphere H.S or LS or N/A proerties ion…

A: The coordination sphere is the cation or anion which consists of a ‘system’ of a central atom…

Q: Diethylenetriammine, as given below isa _ligand. HNCH,CH,–Ñ– CH,CH,NH, Select one: a. Tetradentate…

A: Ligand:  A species that donate its lone pair of electrons to metal ion to form coordinate bond.…

Q: (c) The ligands to meta! charge transfer bands (LMCT) increases in the series Col <CoBr <COCI…

A:

Q: b) Given (Ni(CN).F as a complex ion. Answer the questions below based on Valence Bond Theory. i)…

A: According to Valence bond theory: The valence shell electronic configuration of Ni atom is 3d8 4s2…

Q: hich is the only anionic bidentate ligand ? a) bipyridine b) oxalato c) No

A: Ligands are the negatively charged or species with lone pairs which donate their electrons to the…

Q: EtyN: Yotate C-C bond Trans Now bothl@) cis to each other oct both o rans to each other not act as…

A:

Q: a) Naz[Fe(CN)4(en)] b) The complex ion of this compound is known to be diamagnetic. Draw the…

A: Since CN- is a strong field ligand, it forms low spin complex and has large crystal field splitting.…

Q: 23.44 include drawings

A: a.

Q: Co ligand insertion oc | CH, to co co co n-CHOCH, oc čo oc OCH, OCH, čo CHOCH, o0 Co B D E O A O B…

A:

Q: drawing a suitable structure of the complex below "18 Electron Rule" to show that the suit? Solve…

A: The given complex is, [Pt(η5-C5H5)(NO)] 18 electron rule has to be applied for the given complex. If…

Q: H. F3C-M

A: Pi donor means ligand which donate pi electron density to metal . Pi acceptor means metal transfer…

Q: [Ni (NH3) 6] C12 What Dq is the crystal field stability energy of the complex?

A: According to crystal field theory, all the five d-orbitals of metal atoms are degenerate. But when…

Q: Which complex is MOST stable? O A. [Rh(Me)3(co)3] O B. [Rh(OMe)2(acac)2]- o c. [Rh(acac)3] O D.…

A:

Q: b) The high-spin đ complex (Cr(H:O)J* is labile, but the low-spin d' complex ion [Cr(CN)e]* is…

A:

Q: Which coordination complex has the greatest A,? O [ScI,j³- O [Sc(NH,),J³+ O [Sc(H,O),J³* O…

A: Given  Complex = [ ScI6 ]3- , [ Sc ( NH3 )6 ]3+  , [ Sc( H2O)6 ]3+ , [ Sc ( en )3 ]3+ ∆0  = ?

Q: 3) Calculate Ke for the follo concentrations of each speci [D] = 0.25 M. %3D

A:

Q: The weakest ligand among the following is H20.a O "CN.b bO NH3.cO "Br.dO

A: In coordination chemistry, strength if ligand depend upon π accepter, π donar effect.

Q: Why 6-membered metallacycle ring forms a more stable complex compared to a 4-membered metallacycle…

A: A metallacycle  ring is type of heterocyclic ring in which one carbon atom is replaced by one metal…

Q: ligand

A:

Q: The hickel coördinátión compound bis(P,P-dialkylphosphinic-N-ethylamidato-N,S) nickel sounds…

A: If all the electrons of the central atom of a complex molecule are paired up then the compound is…

Q: 1) Determine the d electron configurationof [Ni(CO)4] complex.  A) (e)4(t2)6 B) (e)4(t2)2 C)…

A: CO is a neutral ligand. In [Ni(CO)4], Ni is present as zero oxidation number.  Ni^0 : 3d^84s^2 ~…

Q: A Tt-acceptor ligand_ а. has same effect on Ao as a t-donor ligand. b. decreases Ao С. increases Ao…

A: π acceptor ligands are ligands which contain π-bonds.

Q: (a) Draw the electronic configuration of [NiCl6]3. (b) Determine whether its paramagnetic or…

A: Electronic configuration is defined as the distribution of electrons of an atom or a molecule in…

Q: cal formula of the following coordination compound. Enclose complexes in squa re no counter ions. Do…

A:

Q: Which of the following ligands will increase the value of A,? CN', CO, CI", N3-, en O Ct, N3- CO…

A: The Crystal Field Splitting (Δo) depends upon the nature of the ligands. The ligands which cause…

Q: What is the name of the complex [Al(H2O)2Br4]? O none of these O bisaquaterbromoaluminate(lI) ion O…

A: Option B is correct

Q: Draw the ligand field interaction diagram between a square planar ML, fragment with a N* (nitride)…

A: The ligand approaching here is N3- on the ML4 complex its interaction can be shown with a molecular…

Q: prove that [Ru(OMe)2(PMe3)4] is a paramagnetic high spin octahedral complex using valence bond…

A: According to valancy bond theory we can say that about the hybridisation of the complexes.…

Q: Predict the geometry and number of unpaired spins inthe following four-coordinate complexes:…

A: Co-ordination compounds: These are the chemical compound formed by donation of electron or charges…

Stereochemistry and Isomerism

Stereochemistry deals with the three-dimensional structure and properties of molecules. It explains the arrangement of atoms and their manipulation within a molecule in a 3D structure. Stereochemistry can be dealt with all types of molecules. Based on the stereochemistry of a molecule, the physical and chemical properties of the molecules vary.