Zinc (II) and the ligand L form a product that absorbs strongly at 600 nm. As long as the molar concentration of L exceeds that of zinc (II) by a factor of 5, the absorbance is dependent only on the cation concentration. Neither zinc(l) nor L absorbs at 600 nm. A solution that is 1.60 x 104 M in zinc (1I) and 1.00 x 103 M in L has an absorbance of 0.464 in a 1.00-cm cell at 600 nm. Calculate: The percentage transmittance of this solution - The percent transmittance of this solution in a 2.50-cm cell. - The molar absorptivity of the complex.

Fundamentals Of Analytical Chemistry
9th Edition
ISBN:9781285640686
Author:Skoog
Publisher:Skoog
Chapter24: Introduction To Spectrochemical Methods
Section: Chapter Questions
Problem 24.21QAP
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• Zinc (II) and the ligand L form a product that absorbs
strongly at 600 nm. As long as the molar concentration
of L exceeds that of zinc (II) by a factor of 5, the
absorbance is dependent only on the cation
concentration. Neither zinc(II) nor L absorbs at 600
nm. A solution that is 1.60 x 104 M in zinc (II) and 1.00
x 103 M in L has an absorbance of 0.464 in a 1.00-cm
cell at 600 nm. Calculate:
The percentage transmittance of this solution
- The percent transmittance of this solution in a 2.50-cm
cell.
- The molar absorptivity of the complex.
Transcribed Image Text:Problem solving: • Zinc (II) and the ligand L form a product that absorbs strongly at 600 nm. As long as the molar concentration of L exceeds that of zinc (II) by a factor of 5, the absorbance is dependent only on the cation concentration. Neither zinc(II) nor L absorbs at 600 nm. A solution that is 1.60 x 104 M in zinc (II) and 1.00 x 103 M in L has an absorbance of 0.464 in a 1.00-cm cell at 600 nm. Calculate: The percentage transmittance of this solution - The percent transmittance of this solution in a 2.50-cm cell. - The molar absorptivity of the complex.
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