Lab9 Report

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Georgia Institute Of Technology *

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1310

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Chemistry

Date

Oct 30, 2023

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pdf

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3

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Kinetics of the Iodine Clock Reaction 29 March 2023 CHEM 1212K Laboratory Data and Results Table 1. Initial conditions, temperatures, and average rates of consumption of ascorbic acid for trials 1 6 of the iodine clock reaction. Trial [I ] i (M) [H 2 O 2 ] i (M) Temperature (K) 1 0.111 0.196 2.93E+02 2 0.111 0.098 2.93E+02 3 0.056 0.196 2.93E+02 4 0.111 0.196 3.13E+02 5 0.111 0.196 3.23E+02 6 0.111 0.196 3.33E+02 –Δ[H 2 C 6 H 6 O 6 ]/Δ t (M/s) 2.97E-04 1.32E-04 1.66E-04 1.30E-03 1.20E-03 1.60E-03 Table 2. Absolute temperatures and rate constants for trials of the iodine clock reaction differing only in temperature. Trial k (1/M 1/s) 1/Temperature (1/K) ln k 1 0.0136 3.411E-03 -4.298 4 0.0598 3.193E-03 -2.817 5 0.0551 3.095E-03 -2.899 6 0.0735 3.002E-03 -2.610
Figure 1. Arrhenius Plot (ln(k) As a Function of Inverse Absolute Temperature) y = -4087.3x + 9.8222 R² = 0.8685 -5.000 -4.500 -4.000 -3.500 -3.000 -2.500 -2.000 -1.500 -1.000 -0.500 0.000 2.950E-033.000E-033.050E-033.100E-033.150E-033.200E-033.250E-033.300E-033.350E-033.400E-033.450E-03 ln(k 1/M 1/s) Inverse Temperature (1/K)
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