Identification of Unknown Petroleum Hydrocarbon (1)
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0Glaster
Lab 12
Identification of Unknown Petroleum
Hydrocarbon
By: Courtney Glaster
Lab Partner: Ilene Ferman
1Glaster
Purpose:
In this lab, we are each given an unknown petroleum hydrocarbon. With this unknown, we are to do 4 separate tests to determine its identity. In the first test, we determine the unknown boiling point. To do this we set up a simple boiling apparatus consisting of a thermometer, a test tube, a capillary tube, and a beaker with water. In the second test, we ran a refractive index test using a refractometer. In test three we measure out specified measurements of the unknown into two separate vials determining the unknown
density. Now in the last test, we carefully prepared an NMR tube and ran it through a machine assisted by
a teacher to get a graph. Background:
What are petroleum hydrocarbons?
A hydrocarbon on its own is defined as an organic compound that consists of only carbon and hydrogen atoms. A petroleum hydrocarbon on the other hand is created when a “pure” hydrocarbon is contaminated with impurities. In this age, petroleum hydrocarbons range from combustion engines to natural gas used in everyday cooking. Table 1: List of Possible Hydrocarbons
2Glaster
Unknowns
Octan
e
Numb
er
Boiling
Point
(
0
C)
Refractive
index at
20 0
C
Density
(g/mL at
20 0
C)
Cyclohexane
77
81
1.4266
0.779
Cyclopentane
83
49
1.4065
0.746
Hexane
26
69
1.3749
0.659
Heptane
0
98
1.3877
0.684
2,3-dimethylbutane
95
58
1.3750
0.662
Methylcyclohexane
71
101
1.4231
0.769
Methylcyclopentane
82
72
1.4097
0.749
3-methylpentane
75
63
1.3765
0.664
2,2,4-
trimethylpentane
100
99
1.3915
0.692
Unknown # 5
Boiling Point:
My partner Ilene took care of this part herself. Doing so as she was instructed, she filled our given test tube with a few millimeters of our unknown (just enough to cover the bulb of the thermometer). Setting aside the thermometer I myself went to get the beaker and fill it with water, about ¾ the way full. Setting it on the hot plate she turned the heat up to about a three heating the water slowly. Grabbing the test tube she clamped it into place lowering it into the water until the liquid level in the test tube was just below the water level. To the test tube, the placed a capillary tube open end downwards into the unknown. For the last step, she lowered the thermometer into the test tube until the bulb was completely inside the unknown.
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Related Questions
QUESTION 11
Place the following chemical compounds in order from lowest to highest boiling point, where 1 is the lowest and 3 is the highest.
This question requires a handwritten response (see below).
For your handwritten submission: Explain the reasoning for your ranking with reference to the intermolecular force(s) present in pure
samples of each compound
Include sketches of each compound to support your explanations.
✓ Ethanoic acid
OH
✓ Methoxyethane
Butane
arrow_forward
CHM 831A Lab 7 - 2021SP
Q5. Calculate the amount of heat (kcal) released when 50.0 g of water at 100°C hits the
skin and cools down to a body temperature of 37°C.
Q6. Calculate the amount of heat (kcal) released when 50.0 g of steam at 100°C hits the
skin and condenses.
Q7. What is the amount of heat (kcal) when 50.0 g of steam hits the skin, condenses,
and cools down to a body temperature of 37°C?
Lab 7 pg. 8
arrow_forward
You place a drop of each of the following substances on wax paper: water, hexane, 1-butanol, octane, and 1-pentenol. Which substance would be expected to form a drop with the smallest diameter on the wax paper? You may need to look up the structures of the molecules online.
Water
Hexane
1-Pentenol
1-Butanol
Octane
arrow_forward
This graph shows how the vapor pressure of three liquids varies with temperature:
900
800
700
600
500
400
300
200
- octane
- orthoxylene
piperidine
100
100
110
120
130
140
temperature, °C
Use the graph to answer the following questions:
Which liquid is the most volatile?
most volatile:
choose one
Which is the least volatile?
least volatile:
choose one
octane:
What is the normal boiling point of each liquid?
Note: your answer must be within 1°C of the exact
answer to be graded correct.
orthoxylene:
piperidine:
Suppose a beaker of orthoxylene is put inside a
sealed tank containing orthoxylene gas at 118.
degree C and 737. torr. After ten minutes, will there
be more liquid in the beaker, less liquid, or the same
amount?
more
less
the same
vapor pressure, torr
arrow_forward
Rank the following compounds in decreasing order of boiling point.
OIII >1> IV > II
OII > IV > III > I
O III >IV>I>II
IV>1 >> III
|>|||>|| >IV
HO.
111
OH
وكرة
arrow_forward
Preparation of 1-bromobutane (n-Butyl Bromide)
In a 250 ml round-bottomed flask, place 13.5 g (0.13 mol) of sodium bromide, 15 mL of water and 10 mL
(0.11 mol) n-butyl alcohol. Cool the mixture in an ice bath and slowly add 12 ml of concentrated sulfuric
acid in 2 ml portions, while swirling and cooling the flask. • Add a few boiling stones and attach the
reflux condenser. Connect the gas trap (dilute NaOH) to the reflux condenser to absorb any escaping
HBr gas (Figure 4, page 9). • Heat gently until boiling begins and then reflux for 30 minutes noting the
formation of an upper layer of alkyl bromide. • Allow the mixture to cool and reassemble the apparatus
for simple distillation. Distil the mixture into an ice-cooled flask until no more waterinsoluble droplets
come over. At this stage the temperature reaches 110- 15 °C. • Transfer the distillate to a 100 mL
separatory funnel, add about 15 ml water, stopper and shake. Drain the lower layer of butyl bromide
into a flask and discard the…
arrow_forward
Which of the following compounds has the lowest boiling point?
2
He
H
10
thim
bem
temn
megin]
10
Li Be
C
N
F Ne
monphone
15
arge
11
12
13
14
16
17
18
Na Mg
AI Si
ci Ar
26
tromine
35
19
20
21
22
23
24
25
27
28
29
30
31
32
33
34
к Са
Sc Ti vCr Mn Fe Co Ni Cu Zn Ga Ge
As Se Br Kr
etem
41
theum
p m
46
ede
37
38
39
40
42
43
44
45
47
48
49
50
52
53
54
Rb Sr
Zr Nb Mo Tc Ru Rh Pd Ag Cd In Sn
Sb Te
Хе
112
bert
hath
than
hemth
abe
55
56
57-70
71
72
73
74
75
76
77
70
79
82
83
85
Cs Ba
Lu Hf Ta w Re Os Ir
Pt Au Hg TI Pb
Bi Po At Rn
87
85-102
103
104
105
106
107
108
100
110
111
112
114
Fr Ra ** Lr Rf Db Sg Bh Hs Mt Uun Uuu Uub
Uuq
223
61
65
67
70
*Lanthanide series
La Ce Pr Nd Pm Sm Eu Gd
Tb Dy Ho Er Tm Yb
174
**Actinide series
91
92
93
94
95
96
97
99
100
101
102
Ac Th Pa U Np Pu Am Cm Bk Cf Es Fm Md No
pe
pe
Select one:
O a.
CH;CH2CH;CH2OH
O b. C(CH3)4
Oc CH3CH2CH2CH2F
d.
(CH;);COH
O e.
CH;CH2CH;CH2CH3
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I need help with an explanation to these questions. Thank you
arrow_forward
Please answer the following question:
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PLEASE provide an indepth explaniton as I will be using this to study
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This graph shows how the vapor pressure of three liquids varies with temperature:
900 -
800 -
700-
600
500
400.
300
ethylbenzene
pyridine
isobutyl alcohol
200
100-
+++H HHH HHHH
140
100
110
120
130
temperature, °C
Use the graph to answer the following questions:
Which liquid is the most volatile?
most volatile:
choose one
Which is the least volatile?
least volatile:
choose one
ethylbenzene:
What is the normal boiling point of each liquid?
Note: your answer must be within 1°C of the exact
answer to be graded correct.
pyridine:
isobutyl alcohol:
Suppose a beaker of pyridine is put inside a sealed
tank containing pyridine gas at 112. degree C and
692. torr. After ten minutes, will there be more liquid
in the beaker, less liquid, or the same amount?
O less
the same
vapor pressure, torr
arrow_forward
Please identify the compound with the lowest boiling point?
HO.
IV
%3D
ON
OII
arrow_forward
Rank the following organic compounds in order of decreasing their boiling
points:
CH3CH2COOH
CH3COOCH3
CH3CH2CH2OH
CH3CH2CONH2
||
II
IV
Select one:
||>l>I||>IV
l>IV>III>I|
IV>l>II>III
IV>l>IIl>I|
arrow_forward
17a
arrow_forward
This graph shows how the vapor pressure of three liquids varies with temperature:
900
800
700
600
500
400
300
200
octane
- isobutyl alcohol
ethylbenzene
100
03
100
110
120
130
140
temperature, °C
Use the graph to answer the following questions:
Which liquid is the most volatile?
most volatile:
choose one
Which is the least volatile?
least volatile:
choose one
octane:
°C
What is the normal boiling point of each liquid?
Note: your answer must be within 1°C of the exact
answer to be graded correct.
isobutyl alcohol:
ethylbenzene:
Suppose a beaker of isobutyl alcohol is put inside a
sealed tank containing isobutyl alcohol gas at 103.
degree C and 900. torr. After ten minutes, will there
be more liquid in the beaker, less liquid, or the same
more
less
amount?
the same
vapor pressure, torr
arrow_forward
Intermolecular Forces, unit conversions & Partial, total pressure
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How do I approach this question
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This graph shows how the vapor pressure of three liquids varies with temperature:
900
800
700
600
500
400
300
- cyclohexanone
benzaldehyde
dimethyl sulfoxide
200
100
150
160
170
180
190
temperature, °C
Use the graph to answer the following questions:
Which liquid is the most volatile?
most volatile:
choose one
Which is the least volatile?
least volatile:
choose one
cyclohexanone:
What is the normal boiling point of each liquid?
Note: your answer must be within 1°C of the exact
answer to be graded correct.
benzaldehyde:
dimethyl sulfoxide: | °C
Suppose a beaker of benzaldehyde is put inside a
sealed tank containing benzaldehyde gas at 169.
degree C and 704. torr. After ten minutes, will there
be more liquid in the beaker, less liquid, or the same
amount?
more
less
the same
vapor pressure, torr
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Which of the following has the highest boiling point?
ethane, CH3CH3
formaldehyde, HCHO
dimethyl ketone, CH3COCH3
ethyl alcohol, CH3CH2OH
acetic acid, CH3COOH
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101 Chem101
Pt Periodic Table - Ptable
Answered: Using the data in the
cf2o lewis structure - Google Sea X
O X
A app.101edu.co
Question 16 of 34
Submit
Liquid butane is used in cigarette lighters. The boiling point of butane
at 1 atm pressure is -1.0 °C and its AHvap is 22.44 kJ/mol. What is the
pressure (in atm) of the butane in the lighter at 25.0 °C?
atm
1
2
4
C
7
8
9.
+/-
х 100
8:03 PM
12/13/2021
...
arrow_forward
This graph shows how the vapor pressure of three liquids varies with temperature:
900
800
700
600
500
400
300
200
octane
- pyridine
orthoxylene
100
0
100
110
120
130
140
temperature, °C
Use the graph to answer the following questions:
Which liquid is the most volatile?
most volatile:
choose one
Which is the least volatile?
least volatile:
choose one
°C
octane:
What is the normal boiling point of each liquid?
Note: your answer must be within 1°C of the exact
answer to be graded correct.
pyridine:
orthoxylene:
more
Suppose a beaker of pyridine is put inside a sealed
tank containing pyridine gas at 112. degree C and
858. torr. After ten minutes, will there be more liquid
in the beaker, less liquid, or the same amount?
less
the same
vapor pressure, torr
arrow_forward
How much heat is given off by 5.0 g of steam at 100oC as it condenses and cools to 20oC?
2.70 kcal
2.80 kcal
2.89 kcal
3.10 kcal
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What is a claim that can be made about the boiling point of similar chemicals that have carbon?
O The more carbons in the chain the lower the boiling point.
O The more carbons in the chain the higher the boiling point.
O The number of carbons in the chain does not affect the boiling point.
O The carbon compounds do not boil at all.
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Of the following substances, __________ has the highest boiling point.
CH3CH2CH2CH2OH
C2H6
N2
F2
CH3CH2OH
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Arrange carbon tetrafluoride (CF4), ethyl methyl sulfide (CH3SC2H5), dimethyl sulfoxide [(CH3)2S=O], and 2-methylbutane [isopentane, (CH3)2CHCH2CH3] in order of decreasing boiling points.
Answer:
dimethyl sulfoxide (boiling point = 189.9°C) > ethyl methyl sulfide (boiling point = 67°C) > 2-methylbutane (boiling point = 27.8°C) > carbon tetrafluoride (boiling point = −128°C)
SHOW HOW IT IS SOLVED
arrow_forward
This graph shows how the vapor pressure of three liquids varies with temperature:
900
800
700
600
500
400
300
- pyridine
orthoxylene
ethylbenzene
200
100
100
110
120
130
140
temperature, °C
Use the graph to answer the following questions:
most volatile:
choose one
Which liquid is the most volatile?
Which is the least volatile?
least volatile:
choose one
°C
pyridine:
What is the normal boiling point of each liquid?
Note: your answer must be within 1°C of the exact
answer to be graded correct.
°C
orthoxylene:
°C
ethylbenzene:
Suppose a beaker of orthoxylene is put inside a
sealed tank containing orthoxylene gas at 125.
degree C and 431. torr. After ten minutes, will there
be more liquid in the beaker, less liquid, or the same
O more
O less
O the same
amount?
vapor pressure, torr
arrow_forward
From the following compounds, which of the following has the highest Solubility in Water?
From the following compounds, which of the following has the highest Melting Point?
Select your answer.
Ethanol
Octanol
Decanol
Pentanol
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Of C2H5OH and C3H5(OH)3 the one expected to have the higher vapor pressure is ________, and the one expected to have the higher boiling point is ________.
Express your answers as chemical formulas separated by a comma.
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Which has the highest boiling point?
arrow_forward
Predict the relative boiling points for the following molecules, putting the highest at the top of the list.
Molecules (6 items)
(Drag and drop into the appropriate area)
Boiling Points
CH3CH(CH3)CH2CH2CH3
1
CH,CH2NHCH,CH,CH,CH,
CH2(OH)CH2CH2CH;(OH)
N(CH2CH3)3
CH2(NH)CH,CH,CH2(NH2)
CH,C(CHa),CH,CH3
3.
2.
arrow_forward
Let's put all of this together!
Which of the three substances would you predict to
be more soluble in water?
A Ethanol (CH3CH₂OH)
B
C
Dimethyl Ether (H3COCH3)
Propane (CH3CH₂CH3)
arrow_forward
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- QUESTION 11 Place the following chemical compounds in order from lowest to highest boiling point, where 1 is the lowest and 3 is the highest. This question requires a handwritten response (see below). For your handwritten submission: Explain the reasoning for your ranking with reference to the intermolecular force(s) present in pure samples of each compound Include sketches of each compound to support your explanations. ✓ Ethanoic acid OH ✓ Methoxyethane Butanearrow_forwardCHM 831A Lab 7 - 2021SP Q5. Calculate the amount of heat (kcal) released when 50.0 g of water at 100°C hits the skin and cools down to a body temperature of 37°C. Q6. Calculate the amount of heat (kcal) released when 50.0 g of steam at 100°C hits the skin and condenses. Q7. What is the amount of heat (kcal) when 50.0 g of steam hits the skin, condenses, and cools down to a body temperature of 37°C? Lab 7 pg. 8arrow_forwardYou place a drop of each of the following substances on wax paper: water, hexane, 1-butanol, octane, and 1-pentenol. Which substance would be expected to form a drop with the smallest diameter on the wax paper? You may need to look up the structures of the molecules online. Water Hexane 1-Pentenol 1-Butanol Octanearrow_forward
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- Which of the following compounds has the lowest boiling point? 2 He H 10 thim bem temn megin] 10 Li Be C N F Ne monphone 15 arge 11 12 13 14 16 17 18 Na Mg AI Si ci Ar 26 tromine 35 19 20 21 22 23 24 25 27 28 29 30 31 32 33 34 к Са Sc Ti vCr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr etem 41 theum p m 46 ede 37 38 39 40 42 43 44 45 47 48 49 50 52 53 54 Rb Sr Zr Nb Mo Tc Ru Rh Pd Ag Cd In Sn Sb Te Хе 112 bert hath than hemth abe 55 56 57-70 71 72 73 74 75 76 77 70 79 82 83 85 Cs Ba Lu Hf Ta w Re Os Ir Pt Au Hg TI Pb Bi Po At Rn 87 85-102 103 104 105 106 107 108 100 110 111 112 114 Fr Ra ** Lr Rf Db Sg Bh Hs Mt Uun Uuu Uub Uuq 223 61 65 67 70 *Lanthanide series La Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb 174 **Actinide series 91 92 93 94 95 96 97 99 100 101 102 Ac Th Pa U Np Pu Am Cm Bk Cf Es Fm Md No pe pe Select one: O a. CH;CH2CH;CH2OH O b. C(CH3)4 Oc CH3CH2CH2CH2F d. (CH;);COH O e. CH;CH2CH;CH2CH3arrow_forwardI need help with an explanation to these questions. Thank youarrow_forwardPlease answer the following question:arrow_forward
- PLEASE provide an indepth explaniton as I will be using this to studyarrow_forwardThis graph shows how the vapor pressure of three liquids varies with temperature: 900 - 800 - 700- 600 500 400. 300 ethylbenzene pyridine isobutyl alcohol 200 100- +++H HHH HHHH 140 100 110 120 130 temperature, °C Use the graph to answer the following questions: Which liquid is the most volatile? most volatile: choose one Which is the least volatile? least volatile: choose one ethylbenzene: What is the normal boiling point of each liquid? Note: your answer must be within 1°C of the exact answer to be graded correct. pyridine: isobutyl alcohol: Suppose a beaker of pyridine is put inside a sealed tank containing pyridine gas at 112. degree C and 692. torr. After ten minutes, will there be more liquid in the beaker, less liquid, or the same amount? O less the same vapor pressure, torrarrow_forwardPlease identify the compound with the lowest boiling point? HO. IV %3D ON OIIarrow_forward
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