exam 3 chem 141 fall 2015

.docx

School

Grossmont College *

*We aren’t endorsed by this school

Course

120

Subject

Chemistry

Date

Jan 9, 2024

Type

docx

Pages

10

Uploaded by MinisterAnteater3911

Chemistry 141 Name Martin Larter Exam 3A November 7. 2015 Multiple Choice (30 points) Page 5 (14 points) Page 6 (21 points) Page 7 (22 points) Page 8 (15 points) Page 9 (12 points) Total (114 points) Chemistry Formulas and Constants Kinetic energy = ½ mv 2 w = -P V E = Δ x Δmv≥ h 4 π Rate 1 Rate 2 = MW 2 MW 1 G o = -nFE o G = - RTlnK w=dxF E = mc 2 P total = P 1 +P 2 +P 3 +… u = (3RT/MW) ½ H =E M 1 V 1 = M 2 V 2 u = (3RT/MW) ½ G = H - T S P total = P 1 + P 2 + P 3 + … PV = nRT Rate (MW) ( P + n 2 a V 2 ) ( V nb ) = nRT c = λν λ deBroglie = h mv = iMRT P total = P 1 + P 2 + P 3 + … ln ( [ A ] [ A ] o ) =− kt ln ( k 2 k 1 ) = ( E a R ) [ ( 1 T 1 ) ( 1 T 2 ) ] E = E o ( 0.0592 n ) log Q ln ( P 2 P 1 ) = ( ΔH vap R ) [ ( 1 T 1 ) ( 1 T 2 ) ] ν = c λ 1 λ =− R ( 1 n i 2 1 n f 2 ) λ deBroglie = h mv ΔxΔ mv h 4 π Constants F = 9.65 x 10 4 C h = 6.626 x 10 -34 J sec c= 2.9979 x 10 8 m/sec mass electron = 9.109 x 10 -31 kg R E = 2.18 x 10 -18 J e = 1.602 x 10 -19 C R = 0.0821 L atm/mol K = 62.4 L torr/mol K = 8.31 kJ/mol K 1
Grossmont College Periodic Table IA VIIA NOBLE GASES 1 H 1.008 IIA IIIA IVA VA VIA 1 H 1.008 2 He 4.002 3 Li 6.941 4 Be 9.012 5 B 10.81 6 C 12.01 7 N 14.01 8 O 16.00 9 F 19.00 10 Ne 20.18 11 Na 23.00 12 Mg 24.30 IIIB IVB VB VIB VIIB VIII VIII VIII IB IIB 13 Al 27.00 14 Si 28.09 15 P 30.97 16 S 32.06 17 Cl 35.45 18 Ar 39.95 19 K 39.10 20 Ca 40.08 21 Sc 44.96 22 Ti 47.90 23 V 50.94 24 Cr 52.00 25 Mn 54.94 26 Fe 55.85 27 Co 58.93 28 Ni 58.70 29 Cu 63.55 30 Zn 65.38 31 Ga 69.72 32 Ge 72.59 33 As 74.92 34 Se 78.96 35 Br 79.90 36 Kr 83.80 37 Rb 85.47 38 Sr 87.62 39 Y 88.91 40 Zr 91.22 41 Nb 92.91 42 Mo 95.94 43 Tc (99) 44 Ru 101.1 45 Rh 102.9 46 Pd 106.4 47 Ag 107.9 48 Cd 112.4 49 In 114.8 50 Sn 118.7 51 Sb 121.8 52 Te 127.6 53 I 126.9 54 Xe 131.3 55 Cs 132.9 56 Ba 137.3 57 La 138.9 72 Hf 178.5 73 Ta 180.9 74 W 183.9 75 Re 186.2 76 Os 190.2 77 Ir 192.2 78 Pt 195.1 79 Au 197.0 80 Hg 200.6 81 Tl 204.4 82 Pb 207.2 83 Bi 209.0 84 Po (209) 85 At (210) 86 Rn (222) 87 Fr (223) 88 Ra 226.0 89 Ac 227.0 104 Rf (261) 105 Db (262) 106 Sg (263) 107 Bh (262) 108 Hs (265) 109 Mt (266) 110 ?? (269) 58 Ce 140.1 59 Pr 140.9 60 Nd 144.2 61 Pm (147) 62 Sm 150.4 63 Eu 152.0 64 Gd 157.3 65 Tb 158.9 66 Dy 162.5 67 Ho 164.9 68 Er 167.3 69 Tm 168.9 70 Yb 173.0 71 Lu 175.0 90 Th 232.0 91 Pa 231.0 92 U 238.0 93 Np (237) 94 Pu (244) 95 Am (243) 96 Cm (247) 97 Bk (247) 98 Cf (251) 99 Es (252) 100 Fm (257) 101 Md (258) 102 No (259) 103 Lr (260) Lanthanide series 2
Actinide series 3
Multiple Choice (30 points) 1. Which statement is always true according to VSEPR theory? a. The shape of a molecule is determined by the polarity of its bonds. b. The shape of a molecule is determined by the repulsions among all electron groups on the central atom (or interior atoms if there is more than one). c. The shape of a molecule is determined only by repulsions among nonbonding electron groups. d. The shape of a molecule is determined only be repulsions among bonding electron groups. e. none of the above 2. Arrange the ions P 3- , S 2- , Ca 2+ , K + , and Cl - in order of increasing ionic radius, starting with the smallest first. a. Ca 2+ , K + , Cl - , S 2- , P 3- b. P 3- , S 2- , Ca 2+ , Cl - , K + c. P 3- , Ca 2+ , S 2- , K + , Cl - d. K + , Ca 2+ , Cl - , S 2- , P 3- e. P 3- , S 2- , Cl - , K + , Ca 2+ 3. Which one of the following ground-state orbital diagrams only violates Hund's rule ? a. b. c. d. e. 4. Which bond should have the longest length? a. N=N b. N-N c. N≡N d. All three bond lengths should be about the same. e. Impossible to determine from the data given 5. Which of these statements correctly describes the use of formal charge in choosing between possible Lewis structures to describe a molecule? I. Formal charge on all the atoms should be zero, or at least the smallest possible value. II. The sum of the formal charges on all the atoms should equal the charge on the molecule or ion. III. The formal charge on an atom is not affected by the electronegativity of the atom. IV. In an anion containing nitrogen and oxygen, the Lewis structures with a negative charge on the nitrogen will contribute the most to the description of the bonding. a. III and IV only b. I and III only c. II and III only d. II and IV only e. I and II only 6. In general, resonance ________ electrons and ________ molecules. a. delocalizes; destabilizes b. delocalizes; stabilizes c. destabilizes; destabilizes d. localizes; stabilizes e. localizes; destabilizes 7. Which type of molecular orbital is used to describe electron density building up above and below the internuclear axis to form a bond? a. π b. * c. * d. e. s 4
Your preview ends here
Eager to read complete document? Join bartleby learn and gain access to the full version
  • Access to all documents
  • Unlimited textbook solutions
  • 24/7 expert homework help