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Analysis Of Elock-Eval Pyrolysis

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Few of the outcrop samples were subjected forRock-Eval pyrolysis because most of them with low TOC values. The average S2(mg HC/g rock ) and hydrogen index (mg HC/g TOC) values of the examined well samples is 4.22and 202 respectively. These values and thecross plot of hydrogen index (HI)versus Tmax and S2 versus TOC (Fig.2 and 3)indicate that the kerogen contained in these rocksis mixed II-III. This result is supported by organic petrological study, which indicated that the organic matter is mixed of marine and terrestrial origin; marine organic matter is dominated by alginite and bituminite, whereas the terrestrial organic matter is dominated by sporinite with minor amounts of vitrinite (Alkhafaji, 2017).

Figure 2: TOC versus S2 …show more content…

VR% values, which were measured from a few particles found in few well samples, were between 0.35-0.49%. These VR% values are in agreement with Tmax data which indicates that the organic matter is immature. The organic matters of the present study are highly yellow fluorescent and some of them are shiny under the blue light excitation, indicating low thermal maturity level. This low level of maturity of these shales is also supported by molecular geochemistry study represented by the medium Pr/nC17 and Ph/nC18 ratios, which got an average of (0.27) and (0.46) respectively (Table 2). Thermal gradient of the interval 1050-1450 m is 2.37 C0/100m in Akkas-1 well; and the present-day temperature between 45 and 55 C0 in this interval (Majedee, 1999). This temperature indicates that the contained organic matter within these shales of this interval is immature (Peters and Cassa, 1994).
Table 2: Some of normal alkanes parameters
Sample Depth (m) Pr/Ph Pr/C17 Ph/C18 outcrop - 1.02 0.27 0.44
Outcrop - 1.60 0.27 0.51
Outcrop - 1.32 0.22 0.38
Outcrop - 1.16 0.24 0.47
Outcrop - 1.45 0.23 0.42
Ak-1 1330 1.31 0.30 0.51
Ak-1 1365 1.09 0.30 0.50
Ak-1 1400 1.81 0.25 0.46
Ak-3 1233 0.96 0.33 0.47
Ak-3 1243 0.83 0.32 0.47

Depositional environment:
The total sulfur content (TS) was measured for some outcrop and well samples. The TSvalues, which represents pyritic sulfur, are generally low in the

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