1) Write the structure of the indicated isomers. Give their IUPAC names.a. All possible chain isomers of (CH,), Cb. Position isomers of cyclohexenolc. Functional isomer of acetophenoned. Functional isomer of butanethiol2. Give the structure and IUPAC names of all possible skeletal isomers of 1-heptyne.

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Chemistry: The Molecular Science

5th Edition

ISBN:9781285199047

Author:John W. Moore, Conrad L. Stanitski

Publisher:John W. Moore, Conrad L. Stanitski

Chapter2: Chemical Compounds

Section2.9: Organic Molecular Compounds

Problem 2.11E

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Distinguish between isomerism and resonance. Distinguish between structural and geometric isomerism. When writing the various structural isomers, the most difficult task is identifying which are different isomers and which are identical to a previously written structurethat is, which are compounds that differ only by the rotation of a carbon single bond. How do you distinguish between structural isomers and those that are identical? Alkenes and cycloalkanes are structural isomers of each other. Give an example of each using C4H8. Another common feature of alkenes and cycloalkanes is that both have restricted rotation about one or more bonds in the compound, so both can exhibit cis- trans isomerism. What is required for an alkene or cycloalkane to exhibit cis-trans isomerism? Explain the difference between cis and trans isomers. Alcohols and ethers are structural isomers of each other, as are aldehydes and ketones. Give an example of each to illustrate. Which functional group in Table 21-4 can be structural isomers of carboxylic acids? What is optical isomerism? What do you look for to determine whether an organic compound exhibits optical isomerism? 1-Bromo-1-chloroethane is optically active whereas 1-bromo-2-chloroethane is not optically active. Explain.
Consider the following proposed structures for benzene, each of which is consistent with the molecular formula C6H6. (iv) CH3CCCCCH3 (v) CH2=CHCCH=CH2 When benzene reacts with chlorine to give C6H5Cl, only one isomer of that compound forms. Which of the five proposed structures for benzene are consistent with this observation? When C6H5Cl reacts further with chlorine to give C6H4Cl2, exactly three isomers of the latter compound form. Which of the five proposed structures for benzene are consistent with this observation?
Organic Chemistry Explain your solution in a step by step fashion. Explain everything clearly and do not leave out any major or minor steps or details. Provide a thoughtful explanation to the question. In other words, provide your reasoning for why you picked your answer. Why are the molecules enantiomers? etc
Write the structures of cis-2-butene and trans-2-butene. Circle the stereoisomer with the higher melting point. Explain why.
The skeletal line formula for a branched alkene is shown below. (i) What is the molecular formula of this compound? (ii) How many carbon atoms are in the longest chain, ignoring the double bond? (iii) What is the longest chain incorporating both carbons of the double bond? (iv) How many substituents are on this chain? (v) Give the IUPAC name for this compound. [6]

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1) Write the structure of the indicated isomers. Give their IUPAC names. a. All possible chain isomers of (CH), C b. Position isomers of cyclohexenol c. Functional isomer of acetophenone d. Functional isomer of butanethiol