1. A pleasant smelling liquid having a boiling point of 101°C. What is the structure of this compound? Major IR Absorptions Major lons in the MS 2880-2980 cm-¹ 29 1737 (str) 41 56 1194 (str) 1166 (str) 57 (base) 73 85 101 (small) 116 (molecular ion) 100 1737 500 vavenumber cm'l 57 Transmittance %T liquid film sample 100 80 0 4000 Relative Intensity е 60 40 20 0 10 81 20 2977 5000 2876 30 40 2000 50 56 60 70 1500 73 80 1194 1166 90 1000 101 100 110 M 116

Organic Chemistry
8th Edition
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Chapter14: Mass Spectrometry
Section: Chapter Questions
Problem 14.27P: Following is the mass spectrum of an unknown compound. The two highest peaks are at m/z 120 and 122....
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1. A pleasant smelling liquid having a boiling point of 101°C. What is the structure of this compound?
Major IR Absorptions
Major lons in the MS
2880-2980 cm-¹
29
41
1737 (str)
1194 (str)
1166 (str)
56
57 (base)
73
85
101 (small)
116 (molecular ion)
100
1737
500
vavenumber cm-1
157
Transmittance %T
ģ
0.
liquid film
sample
100
80
60
4000
Relative Intensity
9
20
0
10
20
2977
9000
2876
30
4.
40
2000
50
56
60
m/z
70
1500
73
80
1194
85
1166
90
1000
101
repla
100
110
M:
116
Transcribed Image Text:1. A pleasant smelling liquid having a boiling point of 101°C. What is the structure of this compound? Major IR Absorptions Major lons in the MS 2880-2980 cm-¹ 29 41 1737 (str) 1194 (str) 1166 (str) 56 57 (base) 73 85 101 (small) 116 (molecular ion) 100 1737 500 vavenumber cm-1 157 Transmittance %T ģ 0. liquid film sample 100 80 60 4000 Relative Intensity 9 20 0 10 20 2977 9000 2876 30 4. 40 2000 50 56 60 m/z 70 1500 73 80 1194 85 1166 90 1000 101 repla 100 110 M: 116
a. methyl
2,2-dimethylpropanoate
b. methyl 2,3-dimethyl propanoate
c. methyl 1,3-dimethyl propanoate
d. none of the above
Transcribed Image Text:a. methyl 2,2-dimethylpropanoate b. methyl 2,3-dimethyl propanoate c. methyl 1,3-dimethyl propanoate d. none of the above
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