1. Calculate the AH for the reaction 2S + 20F 2(g) SO + SF 4(g) (), using the following thermochemical reactions: OF + H,O + 2H,0 S. + Ozia) + 2HF, AH = -277 kJ - 2 (g) SF, + 4HF () AH = -828 kJ %3D AH = -297 kJ
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Q: 1. Calculate the AHO for the reaction 2S + 20F, 2(g) SO (9) + SF 2 (g) 4(g) rxn 6), using the…
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- 4. Anammox bacteria are known to obtain energy from the anaerobic autotrophic oxidation of one mole of NH4+ with N02- to form one mole of N2. (1) Develop an electron equivalent energy reaction for the anammox organisms. (2) Calculate ΔGr (kJ/1nol) for this reaction. (3) Calculate fs° for the anammox autotrophic reaction, assuming ε =0.4, N02- is the N source, inorganic carbon is the carbon source and Y is in g VSS/g N.An impure sample of Na3PO3 weighing 0.1392 g was dissolved in 25 mL of water. A solution containing 50 mL of 3% w/v mercury(II) chloride, 20 mL of 10% w/v sodium acetate, and 5 mL of glacial acetic acid was then prepared. The solution containing the phosphite was added dropwise to the second solution, oxidizing PO3^3– to PO4^3– and precipitating Hg2Cl2. After digesting, filtering, and rinsing, the precipitated Hg2Cl2 was found to weigh 0.4320 g. Report the purity of the original sample as %w/w Na3PO3. Moles Na3PO3 = moles Hg2Cl2ethylene oxide is produced by oxidation of ethylene 100 kmol of ethylene and 100 kmol of o2 are charged to a reactor.the % conversion of ethylene is 85 and%yield of ethylene oxide is 94.12 .calculate the composition of product stream leaving the reactor .the reactions takes place are
- 1. Calculate the heat evolved when 13.56g of oxygen gas (O2) is used to burn white phosphorus at standard temperature and pressure according to the equation: P4(s) + 5O2(g) → P4O10(s), ΔH = -3013 kJ/mol2. Calculate the ΔH for the reaction: B2H6(g) + 6Cl2(g) → 2BCl3(g) + 6HCl(g)The following are given:a. BCl3(g) + 3H2O(l) → H3BO3(g) + 3HCl(g) ΔH = -112.5 kJb. B2H6(g) + 6H2O(l) → 2H3BO3(g) + 6H2(g) ΔH = -493.4 kJc. 1/2H2(g) + 1/2Cl2(g) → HCl(g) ΔH = -92.3 kJconsider the balance to reaction 6 A + 9 B -> 3C + 5D If 6.448 moles of A (MW = 39.34) are consumed, how many moles of B (MW = 42.66) are also consumed?A solution containing 0.402 49 g of CoCl2 ? xH2O (a solid with an unknown number of waters of hydration) was exhaustively electrolyzed to deposit 0.099 37 g of metallic cobalt on a platinum cathode by the reaction Co21 1 2e2¡Co1s2. Calculate the number of moles of water per mole of cobalt in thereagent. A good approach is to find moles of Co, moles of CoCl2, mass of CoCl2, and, by difference, mass of H2O in the sample.
- Many applications of electrochemistry have been in chemical analysis.Suppose a Fe|Fe2+ concentration cell is set-up in which the [Fe2+] = 1.0 x10¯2 M in one compartment but the concentration in the othercompartment is unknown. The Ecell was measured at 0.024V when thehalf-cells were connected.(i) Without doing a numerical calculation, is the unknown more orless concentrated than the 1.0 x 10¯2 M solution? Justify youranswerA piece of an unknown weighing 12.50is placed in 49.7cm of water in a cylinder. The water level increases to 69.0cm3. whats the calculated value for the drnsity of the solid in g ml-1If a dilute H2 SO4 solution is electrolyzed with copper electrodes, the most likely electrode reactions are 2H ^ + + 2e- = H2 (g) at the cathode and 2Cu (s) + H2O = Cu2O (s) + 2H ^ + + 2e- at the anode. If we observe the formation of 27.4 cm3 of moist hydrogen (751 barometric torrs, 23.3 ° C) at the cathode, what change in weight will there be simultaneously at the anode? Data: Pv H2O 23.3 ° C = 22 torr.Atomic mass: Cu (65); O (16); H (1)
- Many applications of electrochemistry have been in chemical analysis.Suppose a Fe|Fe2+ concentration cell is set-up in which the [Fe2+] = 1.0 x10¯2 M in one compartment but the concentration in the othercompartment is unknown. The Ecell was measured at 0.024V when thehalf-cells were connected.(i) Without doing a numerical calculation, is the unknown more orless concentrated than the 1.0 x 10¯2 M solution? Justify youranswer(ii) Calculate the unknown concentration.(iii) Does your calculated answer agree with your original answer?Why?1. Using information from the table above, write a net-ionic equation for the reaction between the Sn electrode and the Cu(NO3)2 solution that would be thermodynamically favorable. Justify that the reaction is thermodynamically favorable. 2. Calculate the value of ∆G° for the reaction. Include units with your answer.Given the Ellingham diagram, write the overall reaction if 2 Mg(s) + O2(g) -> 2 MgO(s) is coupled with the reduction of FeO(s) to Fe(s). Is the overall reaction spontaneous at 800 °C? Justify your answer. Also, write the overall reaction for the extraction of (1) Fe, (2) Al, and (3) Mg from their corresponding metal oxides when coupled with the oxidation of C(s) to CO(g). Which of these metals can be extracted from its oxide at 1800 °C?