Answered: 1. If there is intermolecular hydrogen…

1. If there is intermolecular hydrogen bonding, there also exists another type- intramolecular hydrogen bond. How does an intramolecular hydrogen bond differ from an intermolecular hydrogen bond?

Chemistry: An Atoms First Approach

2nd Edition

ISBN:9781305079243

Author:Steven S. Zumdahl, Susan A. Zumdahl

Publisher:Steven S. Zumdahl, Susan A. Zumdahl

Chapter9: Liquids And Solids

Section: Chapter Questions

Problem 13Q: In the diagram below, which lines represent the hydrogen bonding? a. the dotted lines between the...

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I. If there is intermolecular hydrogen bonding, there also exists another type-
intramolecular hydrogen bond. How does an intramolecular hydrogen bond differ from an
intermolecular hydrogen bond?

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Classify each of the following statements as true or false. a Intermolecular attractions are stronger in liquids than in gases. b Substances with weak intermolecular attractions generally have low vapor pressures. c Liquids with high molar heats of vaporization usually are more viscous than liquids with low molar heats of vaporization. d A substance with a relatively high surface tension usually has a very low boiling point. e All other things being equal, hydrogen bonds are weaker than induced dipole or dipole forces. f Induced dipole forces become very strong between large molecules. g Other things being equal, nonpolar molecules have stronger intermolecular attractions than polar molecules. h The essential feature of a dynamic equilibrium is that the rates of opposing changes are equal. i Equilibrium vapor pressure depends on the concentration of a vapor above its own liquid. j The heat of vaporization is equal to the heat of fusion, but with opposite sign. k The boiling point of a liquid is a fixed property of the liquid. l If you break shatter an amorphous solid, it will break in straight lines, but if you break a crystalline solid, it will break in curved lines. m Ionic crystals are seldom soluble in water. n Molecular crystals are nearly always soluble in water. o The numerical value of heat of vaporization is always larger than the numerical value of heat of condensation. p The units of heat of fusion are kJ/gC. q The temperature of water drops while it is freezing. r Specific heat is conerned with a change in temperature.
What are intermolecular forces? How do they differ from intramolecular forces? What are dipole-dipole forces? How do typical dipole-dipole forces differ from hydrogen bonding interactions? In what ways are they similar? What are London dispersion forces? How do typical London dispersion forces differ from dipole-dipole forces? In what ways are they similar? Describe the relationship between molecular size and strength of London dispersion forces. Place the major types of intermolecular forces in order of increasing strength. Is there some overlap? That is, can the strongest London dispersion forces be greater than some dipole-dipole forces? Give an example of such an instance.
Define the following and give an example of each: (a) dispersion force (b) dipole-dipole attraction (c) hydrogen bond
Cooking oil floats on top of water. From this observation, what conclusions can you draw regarding the polarity or hydrogen-bonding ability of molecules found in cooking oil?
In the diagram below, which lines represent the hydrogen bonding? a. the dotted lines between the hydrogen atoms of one water molecule and the oxygen atoms of a different water molecule b. the solid lines between a hydrogen atom and oxygen atom in the same water molecule c. Both the solid lines and dotted lines represent hydrogen bonding. d. There are no hydrogen bonds represented in the diagram.
Methane (CH4) cannot be liquefied at room temperature, no matter how high the pressure. Propane (C3H8), another simple hydrocarbon, has a critical pressure of 42 atm and a critical temperature of 96.7 C. Can this compound be liquefied at room temperature?

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