1. Reaction S: Cr(CO)e+ PH3 Cr(CO)s(PH3) + Co Reaction T: Mo(CO)p + Cl- Mo(CO)sCI + CO Choose the reaction that likely to proceed via associative mechanism. Explain your answer by elaborating the factors that favor the mechanism.

1. Reaction S: Cr(CO)e+ PH3 Cr(CO)s(PH3) + Co Reaction T: Mo(CO)p + Cl- Mo(CO)sCI + CO Choose the reaction that likely to proceed via associative mechanism. Explain your answer by elaborating the factors that favor the mechanism.

Appl Of Ms Excel In Analytical Chemistry

2nd Edition

ISBN:9781285686691

Author:Crouch

Publisher:Crouch

Chapter13: Kinetic Methods

Section: Chapter Questions

Problem 8P

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Question

1. Reaction S: Cr(CO)s+ PH3
Cr(CO)s(PH3) + CO
Reaction T: Mo(CO)s + Cl-
Mo(CO):CI + CO
(i)
Choose the reaction that likely to proceed via associative mechanism.
(ii)
Explain your answer by elaborating the factors that favor the mechanism.

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