A. Put the following complexes in decreasing order of reactions rates under a dissociation reaction: [CuCl6]-5, [VCI6]3 and [CoCl6]4. Justify. B. Which complexes is more labile, [Mn(H2O)6]2+ or [Mn(NC)614- and why? C. How does the chelate effect affects the rate of a reaction? D. An (inner, outer) sphere mechanism involves liated tbrough a bridaing the electron transfer me

Chemistry & Chemical Reactivity
9th Edition
ISBN:9781133949640
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Chapter22: The Chemistry Of The Transistion Elements
Section: Chapter Questions
Problem 69SCQ
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Solve atleast 2 any of these
A. Put the following complexes in decreasing order of
reactions rates under a dissociation reaction:
[CuCl6]-5, [VCI6]3 and [CoCl6]-4. Justify.
B. Which complexes is more labile, [Mn(H2O)6]2+ or
[Mn(NC)6]4 and why?
C. How does the chelate effect affects the rate of a
reaction?
D. An
the electron transfer mediated through a bridging
ligand. Marcus Theory was developed as to provide
evidence for
mechanisms in electron transfer reactions. The Frank-
Condon principle is used to explain the mechanism of
(inner, outer) sphere mechanism involves
(inner, outer) sphere
an
(inner, outer) sphere reaction.
Transcribed Image Text:A. Put the following complexes in decreasing order of reactions rates under a dissociation reaction: [CuCl6]-5, [VCI6]3 and [CoCl6]-4. Justify. B. Which complexes is more labile, [Mn(H2O)6]2+ or [Mn(NC)6]4 and why? C. How does the chelate effect affects the rate of a reaction? D. An the electron transfer mediated through a bridging ligand. Marcus Theory was developed as to provide evidence for mechanisms in electron transfer reactions. The Frank- Condon principle is used to explain the mechanism of (inner, outer) sphere mechanism involves (inner, outer) sphere an (inner, outer) sphere reaction.
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