1. The 'H and "C NMR spectra of compound A are shown below. In the mass spectrum the parent ion appears at m/z= 129. In the 'H spectrum there are two nearly coincident resonances (1.01 and 1.02 ppm). a) What is the molecular formula of A? 20.8 48.6

Organic Chemistry
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Author:John E. McMurry
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Chapter12: Structure Determination: Mass Spectrometry And Infrared Spectroscopy
Section12.SE: Something Extra
Problem 48AP: The infrared spectrum of the compound with the mass spectrum shown below lacks any significant...
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1. The 'H and 'C NMR spectra of compound A are shown below. In the mass spectrum the parent ion
appears at m/z= 129. In the 'H spectrum there are two nearly coincident resonances (1.01 and 1.02
ppm).
%3D
a)
What is the molecular formula of A?
20.8
48.6
39.1
17.2
200
180
160
140
120
100
80
60
40
20
ppm
b)
What is the structure of A?
1.02 ppm
(d, 12H)
1.01 ppm
(t 3H)
Transcribed Image Text:1. The 'H and 'C NMR spectra of compound A are shown below. In the mass spectrum the parent ion appears at m/z= 129. In the 'H spectrum there are two nearly coincident resonances (1.01 and 1.02 ppm). %3D a) What is the molecular formula of A? 20.8 48.6 39.1 17.2 200 180 160 140 120 100 80 60 40 20 ppm b) What is the structure of A? 1.02 ppm (d, 12H) 1.01 ppm (t 3H)
200
180
160
140
120
100
80
60
40
20 0
ppm
b),
What is the structure of A?
1.02 ppm
(d, 12H)
1.01 ppm
(t, 3H)
2.47 ppm
3.02 ppm
(q, 2H)
(m, 2H)
11
10
8 7
6.
4 3
1
ppm
EGO
2.
9.
Transcribed Image Text:200 180 160 140 120 100 80 60 40 20 0 ppm b), What is the structure of A? 1.02 ppm (d, 12H) 1.01 ppm (t, 3H) 2.47 ppm 3.02 ppm (q, 2H) (m, 2H) 11 10 8 7 6. 4 3 1 ppm EGO 2. 9.
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