1.96 Initial pH From your analysis of the titration curve: 23.203 mL of NaOH used to reach the equivalence point. Calculated Molarity of the unknown acid 0.09696 2.92 pH at the half-way to the equivalence point pKa the unknown acid Ka of the unknown acid Identity of unknown acid

Chemistry: Principles and Reactions
8th Edition
ISBN:9781305079373
Author:William L. Masterton, Cecile N. Hurley
Publisher:William L. Masterton, Cecile N. Hurley
Chapter14: Equilibria In Acid-base Solutions
Section: Chapter Questions
Problem 32QAP: Enough water is added to the buffer in Question 30 to make the total volume 5.00 L. (a) Calculate...
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unbe
10. Use the volume of NaOH used to reach the equivalence point, the given molarity of the NaOH used,
and the volume of acid used to calculate the molarity of the acid.
11. Find the pH at the point when 2 of the NaOH needed to reach the equivalence was added. Use
this to find the pka of the acid, and the Ka of the acid.
12. Using your value of Ka, identify your unknown acid. Possible unknowns are listed in table below.
Name
Formula
Ка
pKa
Аcetic acid
HC2H3O2
1.76 x 10-5
4.75
Sodium bisulfite
NaHSO4
1.02 x 10-2
1.99
Formic acid
HCHO2
1.77 x 10-4
3.75
Propionic Acid
C3H6O2
1.34 x 10-5
4.87
Chloroacetic Acid
HCICH2O2
1.40 x 10-3
2.85
13. Print a copy of the graph of the titration. You can print the graph directly from LabQuest.
Part D: Addition of an acid and base to a buffer solution
1. In order to create a buffer, add 20.00mL of your weak acid into
a clean 125 mL flask using a pipette.
Transcribed Image Text:unbe 10. Use the volume of NaOH used to reach the equivalence point, the given molarity of the NaOH used, and the volume of acid used to calculate the molarity of the acid. 11. Find the pH at the point when 2 of the NaOH needed to reach the equivalence was added. Use this to find the pka of the acid, and the Ka of the acid. 12. Using your value of Ka, identify your unknown acid. Possible unknowns are listed in table below. Name Formula Ка pKa Аcetic acid HC2H3O2 1.76 x 10-5 4.75 Sodium bisulfite NaHSO4 1.02 x 10-2 1.99 Formic acid HCHO2 1.77 x 10-4 3.75 Propionic Acid C3H6O2 1.34 x 10-5 4.87 Chloroacetic Acid HCICH2O2 1.40 x 10-3 2.85 13. Print a copy of the graph of the titration. You can print the graph directly from LabQuest. Part D: Addition of an acid and base to a buffer solution 1. In order to create a buffer, add 20.00mL of your weak acid into a clean 125 mL flask using a pipette.
Volume delivered
Molarity of unknown acid
Part C: Titration of unknown monoprotic acid using NaOH and a pH sensor
1.96
Initial pH
From your analysis of the titration curve:
23.203
mL of NaOH used to reach the equivalence point
0.09696
Calculated Molarity of the unknown acid
2.92
pH at the half-way to the equivalence point
pKa the unknown acid
Ka of the unknown acid
Identity of unknown acid
Part D: Addition of an acid and base to a buffer solution
Transcribed Image Text:Volume delivered Molarity of unknown acid Part C: Titration of unknown monoprotic acid using NaOH and a pH sensor 1.96 Initial pH From your analysis of the titration curve: 23.203 mL of NaOH used to reach the equivalence point 0.09696 Calculated Molarity of the unknown acid 2.92 pH at the half-way to the equivalence point pKa the unknown acid Ka of the unknown acid Identity of unknown acid Part D: Addition of an acid and base to a buffer solution
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