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- Pressure was exerted with a piston on molten naphthalene at 95 °C. The vaporpressure of naphthalene when the applied pressure is 1.0 bar is 2.0 kPa. What is thevapor pressure when the pressure on the liquid is 15 MPa? The mass density ofnaphthalene at this temperature is 1.16 g cm-1.The table below shows temperature/composition data collected for a mixture of methylbenzene (M) and octane (O) at 1 atm. Recall that x stands for the mole fraction in the liquid and y stands for the mole fraction in the vapor in equilibrium. The boiling points for methylbenzene (M) and octane (O) are 110.60C and 125.60C, respectively. Construct the phase diagram with Temperature vs. xM. What is the composition of the vapor in equilibrium with the liquid of composition (a) xM = 0.250 and (b) xO = 0.250. T (0C) 110.9 112.0 114.0 115.8 117.3 119.0 121.1 123.0 xM 0.908 0.795 0.615 0.527 0.408 0.300 0.203 0.097 yM 0.923 0.836 0.698 0.624 0.527 0.410 0.297 0.164The solvent for an organic reaction is prepared by mixing 70.0 mL of acetone (C3H6OC3H6O) with 56.0 mL of ethyl acetate (C4H8O2C4H8O2). This mixture is stored at 25.0 ∘C∘C. The vapor pressure and the densities for the two pure components at 25.0 ∘C∘C are given in the following table. What is the vapor pressure of the stored mixture? Compound Vapor pressure(mmHg) Density(g/mLg/mL) acetone 230.0 0.791 ethyl acetate 95.38 0.900
- For a given liquid a plot of the lnP versus 1/T gives a straight line with a slope of -4423 K. What is the ΔHvap of this liquid? Your answer should be in kJ/mol and have 3 sig figsFor a given liquid a plot of the lnP versus 1/T gives a straight line with a slope of -2829 K.What is the ΔHvap of this liquid? Your answer should be in kJ/mol and have 3 sig figsCalculate the change in freezing point of water , with ethalpy of fusion = 6.009 kJ/mole) and the density of ice is 0.9167 g/cc while for that liquid is 0.9999 g/cc for an increase in pressure of 1.00 atm at 273 K.
- 1. Ideal solution composition of A and B liquids at 80°C is 100 (for A) and 600 (for B) mmHg, respectively. (a) Construct the P-x phase diagram by calculating the compositions of the liquid and vapor phases. (b) 1.0 mole of solution with ZB= 0.60 at 80°C is in an open container and is evaporated until the total vapor pressure decreases by 20%. Calculate the number of moles of the liquid and vapor phases using the leverage rule.Polyethylene glycol 400 (PEG400) is a nonvolatile liquid polymer, which when mixed with water canbe used as a base for parenteral formulations. The designation “400” means that the molecular weightof PEG molecules is approximately 400 g/mol. Preparation with water (ΔHv = 40.7 kJ/mol) requires that the two be mixed at 56 oC, at which the equilibrium vapor pressure of pure water is 16.5 kPa. a. If 105 g of PEG400 are added to 500 g of water at 56 oC, what will the boiling temperature of the solution be?For a given liquid a plot of the lnP versus 1/T gives a straight line with a slope of -4344 K.What is the ΔHvap of this liquid? Your answer should be in kJ/mol and have 3 sig figs(Note, do not include units on your answer, just a number)
- Since the melting point of ice is 0⁰C and its melting enthalpy is 6.010 kJ/mol, calculate the freezing point depression of water at 95 bars and 450 bars. (Assume that the densities of water in liquid and solid state are 0.997 g/ and 0.917 g/cm3 and remain constant.)Crude oil containing 5.0 mole per cent of gasoline is stripped by running the crude down a columnup which live steam is passed so that 15 kmol of steam are used/100 kmol of oil stripped. Determinethe number of theoretical plates required to reduce the gasoline content to 0.05 mole per cent, assumingthat the crude oil is non-volatile. The vapor–liquid relation of the gasoline in the oil is given by ye = 44x,where ye is the mole fraction in the vapor and x the mole fraction in the liquid. The temperature ismaintained constant by internal heating so that steam does not condense in the tower.A vapour solution with a mole percentage of 10% benzene is cooled gradually. At what temperature does liquid first appear?