105. Mechanism of NO, Destruction Which of the following mechanisms are possible for the thermal decomposition of k[NO3]? NO2, given that the rate = slow → NO(g) + O(g) NO(g) + O2(g) NO;(g) a. fast O(g) + NO2(g) b. NO2(g) + NO,(g) fast → N2O4(g) slow NO(g) + NO3(g) NO(g) + O2(g) NO(g) + NO3(g) NO(g) + O2(g) N,O.(g) NO3(g) fast slow c. NO2(g) + NO;(g) NO3(g fast ,
105. Mechanism of NO, Destruction Which of the following mechanisms are possible for the thermal decomposition of k[NO3]? NO2, given that the rate = slow → NO(g) + O(g) NO(g) + O2(g) NO;(g) a. fast O(g) + NO2(g) b. NO2(g) + NO,(g) fast → N2O4(g) slow NO(g) + NO3(g) NO(g) + O2(g) NO(g) + NO3(g) NO(g) + O2(g) N,O.(g) NO3(g) fast slow c. NO2(g) + NO;(g) NO3(g fast ,
Organic Chemistry: A Guided Inquiry
2nd Edition
ISBN:9780618974122
Author:Andrei Straumanis
Publisher:Andrei Straumanis
Chapter13: Substitution
Section: Chapter Questions
Problem 43CTQ
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Question
![Temp/Temp1_Gilbert_5th_Edition
_Chemistry_Science_n.context.pdT.zip/Glibert_5th_Edition_Chemistry_Scl..
Not syn
D Page view A Read aloud
▼ Draw
9 Highlight
O Erase
四
of the two elementary steps (specifically, relative rate and
reversibility) are consistent with this mechanism?
105. Mechanism of NO, Destruction Which of the following
mechanisms are possible for the thermal decomposition of
NO2, given that the rate = k[NO2]??
NO,(g)
slow
→ NO(g) + 0(g)
NO(g) + O2(g)
a.
fast
O(g) + NO,(g)
b. NO,(g) + NO2(g)
fast
> N2O4(g)
slow
NO(g) + NO;(g)
→ NO(g) + O2(g)
→ NO(g) + NO3(g)
NO(g) + O,(g)
N,O4(g)
fast
NO;(g)
slow
c. NO2(g) + NO,(g)
с.
fast
NO3(g)
106. The rate laws for the thermal and photochemical
decomposition of NO, are different. Which of the](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F9d5280c1-0888-4121-94fb-2a368f5b3705%2F6756831b-0b2f-4b9c-b9ae-384920faf477%2F5s3h63_processed.jpeg&w=3840&q=75)
Transcribed Image Text:Temp/Temp1_Gilbert_5th_Edition
_Chemistry_Science_n.context.pdT.zip/Glibert_5th_Edition_Chemistry_Scl..
Not syn
D Page view A Read aloud
▼ Draw
9 Highlight
O Erase
四
of the two elementary steps (specifically, relative rate and
reversibility) are consistent with this mechanism?
105. Mechanism of NO, Destruction Which of the following
mechanisms are possible for the thermal decomposition of
NO2, given that the rate = k[NO2]??
NO,(g)
slow
→ NO(g) + 0(g)
NO(g) + O2(g)
a.
fast
O(g) + NO,(g)
b. NO,(g) + NO2(g)
fast
> N2O4(g)
slow
NO(g) + NO;(g)
→ NO(g) + O2(g)
→ NO(g) + NO3(g)
NO(g) + O,(g)
N,O4(g)
fast
NO;(g)
slow
c. NO2(g) + NO,(g)
с.
fast
NO3(g)
106. The rate laws for the thermal and photochemical
decomposition of NO, are different. Which of the
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