12 Which one of these amino esters can produce a hemiacetal when treated with formaldehyde? MeN-CHC-OMe MeN-CHC-OMe Me,N-ÇHÖ-OMe Me,N-CHC-OMe CH2 CH2 COMe Me C=0 OH B OH D.

Organic Chemistry
8th Edition
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Chapter18: Functional Derivatives Of Carboxylic Acids
Section: Chapter Questions
Problem 18.59P
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12

8. Which species is the first formed intermediate in this acid-catalyzed amide hydrolysis reaction?
Me,NH
NMe
он
OH
OH
NMe
NMe
NMeg
9.
Which one of these amino esters would generate an enamine when treated with acetone?
CO-Me
ÇO,Me
CO-Me
CO,Me
'N'
Ph.
NH
CMes
NH2
Me
Me
ČMe,
A
D
10
Which one of these amino esters would generate an imine when treated with methylamine?
Me,N-CHC-OMe Me,N-CHC-OMe Me,N-CHC-OMe Me;N-CHC-OMe
CH2
CH2
C=0
CH2
CH2
CH2
CO,Me
CH2
Me
он
B
1.
Which one of these amino esters is achiral?
ÇO,Me
ÇO,-Me
ÇO,-Me
CO,Me
Ph.
ZHN.
D.
NH2
ZHN
A
B.
12.
Which one of these amino esters can produce a hemiacetal when treated with formaldehyde?
Me,N-CHC-OMe Me,N-CHC-OMe Me,N-CHC-OMe Me,N-CHC-OMe
CH2
CH2
ÓH
CH2
Me
CH2
CO,Me
B
OH
D.
Transcribed Image Text:8. Which species is the first formed intermediate in this acid-catalyzed amide hydrolysis reaction? Me,NH NMe он OH OH NMe NMe NMeg 9. Which one of these amino esters would generate an enamine when treated with acetone? CO-Me ÇO,Me CO-Me CO,Me 'N' Ph. NH CMes NH2 Me Me ČMe, A D 10 Which one of these amino esters would generate an imine when treated with methylamine? Me,N-CHC-OMe Me,N-CHC-OMe Me,N-CHC-OMe Me;N-CHC-OMe CH2 CH2 C=0 CH2 CH2 CH2 CO,Me CH2 Me он B 1. Which one of these amino esters is achiral? ÇO,Me ÇO,-Me ÇO,-Me CO,Me Ph. ZHN. D. NH2 ZHN A B. 12. Which one of these amino esters can produce a hemiacetal when treated with formaldehyde? Me,N-CHC-OMe Me,N-CHC-OMe Me,N-CHC-OMe Me,N-CHC-OMe CH2 CH2 ÓH CH2 Me CH2 CO,Me B OH D.
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