13. (a) Calculate the pressure of Xe gas using the ideal gas law and the van der Waals equation of state first at a temperature of 30.0°C and a molar volume of 0.200 L mol-¹ and secondly at a temperature of 500°C and a molar volume of 0.200 L mol-¹ (Note: for Xe a = 4.192 dmº bar mol-² and b = 0.0516 dm³ mol-¹) ]For each set of conditions in part (a), calculate the % deviation from the ideal (b) pressure. (c) [ intermolecular Explain the deviation from ideality for each set of conditions in terms of forces, temperature, and the effect of the size of the Xe atoms as appropriate.

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Chapter5: Gases
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13. (a) - Calculate the pressure of Xe gas using the ideal gas law and the van der Waals
equation of state first at a temperature of 30.0°C and a molar volume of 0.200 L mol-¹ and secondly
at a temperature of 500°C and a molar volume of 0.200 L mol-¹
(Note: for Xe a = 4.192 dmº bar mol-2 and b = 0.0516 dm³ mol-¹)
]For each set of conditions in part (a), calculate the % deviation from the ideal
(b)
pressure.
1
(c) [
intermolecular
Explain the deviation from ideality for each set of conditions in terms of
forces, temperature, and the effect of the size of the Xe atoms as appropriate.
Transcribed Image Text:13. (a) - Calculate the pressure of Xe gas using the ideal gas law and the van der Waals equation of state first at a temperature of 30.0°C and a molar volume of 0.200 L mol-¹ and secondly at a temperature of 500°C and a molar volume of 0.200 L mol-¹ (Note: for Xe a = 4.192 dmº bar mol-2 and b = 0.0516 dm³ mol-¹) ]For each set of conditions in part (a), calculate the % deviation from the ideal (b) pressure. 1 (c) [ intermolecular Explain the deviation from ideality for each set of conditions in terms of forces, temperature, and the effect of the size of the Xe atoms as appropriate.
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