13–12. Given that R, = 156.0 pm and k = 250.0 N-m- for 'Li"F, use the rigid rotator-harmonic ocillator approximation to construct to scale an energy-level diagram for the first five rotational levels in the v = 0 and v = 1 vibrational states. Indicate the allowed transitions in an absorption experiment, and calculate the frequencies of the first few lines in the R and P branches of the vibration-rotation spectrum of “Li®F. %3D

13–12. Given that R, = 156.0 pm and k = 250.0 N-m- for 'Li"F, use the rigid rotator-harmonic ocillator approximation to construct to scale an energy-level diagram for the first five rotational levels in the v = 0 and v = 1 vibrational states. Indicate the allowed transitions in an absorption experiment, and calculate the frequencies of the first few lines in the R and P branches of the vibration-rotation spectrum of “Li®F. %3D

Fundamentals Of Analytical Chemistry

9th Edition

ISBN:9781285640686

Author:Skoog

Publisher:Skoog

Chapter27: Molecular Fluorescence Spectroscopy

Section: Chapter Questions

Problem 27.1QAP

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