2) i) Draw a perspective diagram (dash/wedge) of (S)-1-bromo-1-fluoroethane. Only use dash/wedge for the chirality center, and show your C.I.P. priorities to prove the (S)- designation. i) Draw a detailed mechanism showing the formation of the major product(s) of the reaction between (S)-1-bromo-1-fluoroethane and sodium methoxide (NAOCH, the Na" is a spectator). Please be sure to include all structures (use perspective diagrams as appropriate to illustrate the stereochemistry of the process), resonance forms, intermediates, transition states, curved arrows, formal charges, or lone pairs as necessary. iii) Please redraw your product(s) below and assign (R/S) to the chirality center(s) therein. (please show your C.I.P priorities). Is the mechanism SN1 or SN2, and what is the overall stereochemistry associated with the process? Why is this an interesting case?
2) i) Draw a perspective diagram (dash/wedge) of (S)-1-bromo-1-fluoroethane. Only use dash/wedge for the chirality center, and show your C.I.P. priorities to prove the (S)- designation. i) Draw a detailed mechanism showing the formation of the major product(s) of the reaction between (S)-1-bromo-1-fluoroethane and sodium methoxide (NAOCH, the Na" is a spectator). Please be sure to include all structures (use perspective diagrams as appropriate to illustrate the stereochemistry of the process), resonance forms, intermediates, transition states, curved arrows, formal charges, or lone pairs as necessary. iii) Please redraw your product(s) below and assign (R/S) to the chirality center(s) therein. (please show your C.I.P priorities). Is the mechanism SN1 or SN2, and what is the overall stereochemistry associated with the process? Why is this an interesting case?
Principles of Instrumental Analysis
7th Edition
ISBN:9781305577213
Author:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Chapter1: Introduction
Section: Chapter Questions
Problem 1.12QAP
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