2) Write the major products A- P for each of the following reactions. (70 point)HBrCH,CH,OK*CH;CH,OHt-BuO'Ka)Brt-BUOHBr,/ H20FBrKMNO/ OHZn1) 0,2) Zn/ CH;COOHb)BrNANH,CH,CH,IH.Li NH;-78°Cd) Aconcd. H,SO,L.H,O/ HBr, CCl,excess NaNH,hearNH,

Answered: Image /qna-images/answer/2e0e865d-5c51-47af-804e-86729f65a624.jpg

2) Write the major products A- P for each of the following reactions. (70 point) HBr A CH3CH,OK* CH;CH,OH t-BuO'K* t-BUOH a) Br Br/H20 D F Br KMNO/ OH Zn E 1) 03 2) Zn/ CH,COOH b) Br NaNH, CH;CH,I H. Li/ NH3 c) = J -78°C d) - H,O/H coned. H-SO, Br/ CCI excess NaNH, heat NH3

2) Write the major products A- P for each of the following reactions. (70 point) HBr A CH3CH,OK* CH;CH,OH t-BuO'K* t-BUOH a) Br Br/H20 D F Br KMNO/ OH Zn E 1) 03 2) Zn/ CH,COOH b) Br NaNH, CH;CH,I H. Li/ NH3 c) = J -78°C d) - H,O/H coned. H-SO, Br/ CCI excess NaNH, heat NH3

Organic Chemistry: A Guided Inquiry

2nd Edition

ISBN:9780618974122

Author:Andrei Straumanis

Publisher:Andrei Straumanis

Chapter19: Eas: Electrophilic Aromatic Substitution

Section: Chapter Questions

Problem 45E

See similar textbooks

Related questions

Q: ple Cholce Gi Saved Select the corTrect stepwise mechanism for the reaction shown below, which…

Q: using the IUPAC rules name every (all four) molecule.

A: The given structure is, From the structure it is clear that, The longest carbon chain has 7 carbon…

Q: PQ-13. In the dehydrohalogenation of 2-bromo-2- methylbutane with potassium hydroxide, which…

A: The stability of alkene depends on the number of alkyl group present of the double bond carbon atom.…

Q: pls solve this ques within 10-20 minutes in clear handwriting I'll give you multiple upvotes

Q: R & S as Gu: Label te following Suudure CH3 CH Cっ

A: We assign R & S using CIP rule: The four atoms or groups attached to the chiral carbon are…

Q: Vhich atom in the molecule below possesses a partial negative charge as a result of inductive…

A: The molecule given is,

Q: 16 When chie is bud s hot a, the in prodta ied ae A dHo 17. The ethalpy of ng b i57.3K which tute…

A: 16 Cl2 + NaOH ( hot) ---> NaCl + NaClO3 + H2O So answer will be (C) I e Cl-(aq) , ClO3-(aq) and…

Q: Upload answer sheets = 41,000 cm¹ by (a) Explain the reason for the high CFSE value of [Ir(NH3)6]³+…

Q: pase, B, in BH+ + OH¯ B + H2O ization constant B + H+ BH+ B + H½O BH+ + OH- B + OH¯ BH¯ + O²- B…

A: Base ionization constant is the expression of concentration of products to concentration of…

Q: LKJ JKL 5. CH₂-C=C-CH₂ MNO ONM 6.* CH₂CH₂-CECH RQP PQR оо KMnO4, H₂O* heat H₂ Lindlar's catalyst…

A: Potassium permagnate is a strong oxidising agent.

Q: CN 1.H3O*/H,O/heat NH, 2. with „N:C:N, DCC 3. LİAIH,/ THF (solvent) 4. NaOH/H,O (workup)…

A: In the given problem following steps to be followed: Hydrolysis of cyanide group resulting in the…

Q: P ph3 R-CH2-0H >R_CH2-X + Ph + HCX3 X = l or Br write ave mechanis m?

Q: H. Me Me Et Me Me 3 Et. H. H- -H- 12 H H H. H. H. H. H Et H. H H. Et Interaction Energy cost…

A: Total energy cost of the conformation C will be the sum of the energy of all interactions existing…

Q: a) H,CO- 1) SnCl/HCI NO2 2) NAOH/H;O b) Pd B. OH + K½CO/H>O c) ỌH NaOCI (excess) H,0

Q: -C=C H H₂ (excess) Pd/C HgSO4, H₂O H₂SO4 i. BH3/THF ii. NaOH, H₂O₂, H₂O

A: Answer : A) The terminal alkynes produce a ketone under these conditions.

Q: Please explain What is the reaction? cycloaddition 8-8 - & HPh CO₂Me CO₂Me CO₂Me CO₂Me HPh OH 86-00…

Q: Deaw the peoducto of Jequences ohawn belw. Ignore inorganic bproducts. tuwo Step Leaction 1. NacN 2.…

Q: Endicate the product in box and indicate whecis the thermady nami or Kinetic prodaut CampandE 1) quv…

Q: Give a clear explanation handwritten answer...please give answer all sub parts

A: According to the Brønsted-Lowry concept : an acid is a proton donor and a base is a proton acceptor…

Q: Identify all the acidic hydrogens (pKg less than 25) in the following substances. List the acidic…

Q: Oxymercuration- Demercuration Reaction OAc mercurinium ion Hg(OAc) Hg* Oxymercuration-Demercuration…

Q: Draw the products of each reaction, and indicate the stereochemistry where appropriate.

A: (a) In the given reaction, a strong bulky base abstract a proton from alpha position then removal of…

Q: `NH H*

Q: propose seme pessble struetures that fit the date 2a. C. H, O containing compound with MW 100 A…

A: IR spectrum is used for the identification of the functional group present in the molecule. The…

Q: CH,CH,OH CH,CH,NH heat E. press ALT+F10 (PC) or ALT+FN+F10 (Mac). Paragraph Arial 10pt 田田田田田 A.

A: According to the question, we need to determine the reaction product and complete the sequence.…

Q: [Review Topics)] [References Classify the following substituents according to whether they are…

A: Inductive effect depends on electronegativity . If more electronegative substituents then it…

Q: A student ran the reaction shown here separately using two different bases: once with NaOH and again…

Q: item 2 Draw the cycie heactal H u ones f e HO--H HO--H Dreg the aporopriat labals to their pective…

Q: Teken 'n stereoisomeer van 3,4-dihidroksieheksaandioësuur wat ook 'n meso-verbinding Draw a…

Q: What are the produds ? Justily your answers by showng the fill meehanism of the reackon, April 5…

A: When ketones treated with excess of alcohols in Acidic medium, initially hemiketal and finally…

Q: 26) The molecule below is OCH3 OCH, A) Curcumin from turmeric B) Pterostilbene from blueberries C)…

A: Since you have asked multiple question, we will solve the first question for you. If you want any…

Q: NABH4 OH OH LIAIH4 OH OEt H. chemoselectivity How ban do this reaction?

Q: Predict the product of the reaction shown. NaOEt Solvent / heat HDJCMD MacBook Air

A: The details solution for this reaction with mechanism is provided below in attach image.

Q: Calculate the AH of reaction for: C3H8 (@) + 502 (0) The values of AHO are as follows: C3H8 (@) 3CO2…

A: The enthalpy of a reaction can be obtained by the difference between enthalpy of product and…

Q: Find the deltaH for the reaction below, given the following reactions and subsequent deltaH values:…

A: Enthalpy is additive in nature

Q: Show hydrogen bonds and the dipole-dipole moments.

A: Hydrogen Bonding takes place when hydrogen atom of one molecule interacts with the electronegative…

Q: lat is the th CH,CH,OH + H,SO,→ CH,=CH, + H,0 OmL ethanol (MM: 46.07g/mol); ethylene (MM: 28.05);…

A: Given : Volume of ethanol = 10 ml Volume of sulfuric acid = 30 ml

Q: 11.42 Predict products J-N CI 1.2 equiw NaNH- 2. H20

Q: What is a glysodic bond 1,4 mean and 1,6

A: In oligosaccharides and polysaccharides the monosaccharide units are joined by an -O- linkage it is…

Q: Lab 3: Electrophilic Bromination Prelab, Write out the reaction scheme: Trans-stilbene reacting with…

Q: 4 The equilibrinm censtent fer the folbwiny (tachlon is 4.51 xl0-5 at 450 °C Nz CG) +3Hz CG) e-> 2…

A: Given equation : N2(g) + 3H2(g) ---->> 2NH3(g) Keq = 4.51 * 10-5 at 4500C 4NH3(g)…

Q: 2. Give the wet chemcial tests (#1-6) that work for ALDEHYDES onl the p urnec e of m aking aa "d…

A: Aldehydes can be identified by using Fehling's solution, Benedict 's solution, Tollens' s reagent.

Q: NO2 NH2 HN03 Hz, P4/C H2SO4

A: In the electrophilic substitution reaction, electrophiles, such as Cl+, is substituted by the help…

Q: H H.. \PPH3 Rh: insertion A Ph;P" CI H2C=CH2 CO PPH3 -PPH3 Ph3P-Ru 'PPH3 čo +2 Ph-CEC-Ph B.…

Q: 5) A. Showt B. Draw f H H. но он a-D-Fru

A: Anomers are cyclic monosaccharides or glycosides that have difference in configuration either at C-1…

Q: The AH° values of each compound is given below as kJ/mol. Calculate the entaphy change (AH°) value…

Q: Image attached. Provide missing information?

A: Hello. Since your question has multiple sub-parts, we will solve the first three sub-parts for you.…

Q: (е) CH3 OH A OH

A: The two step reaction in which alkene is converted to alcohol in presence BH3/THF and H2O2 is known…

Q: RIGEROUS OX CH3-CH,- OH A) MILD OX B) H*/140°C 2 CH — CH—он C) H20 H* D) H,0 + A) CH3-CH2-OH

Q: AL+ KOH +H20- >KAL(OH)y + Hz 7.07 H, C204 2 H2Q- He C Oy Hz Cz Ou C204?+KAL (OH), K, AL(c Ou), z H20…

Concept explainers

Polymerization Kinetics

Polymerization is a chemical process in which one or more monomers combine to produce a very large chain-like molecule called a polymer. The functional groups present on the monomers and their steric effects are responsible for polymerization through a sequence of reactions that diverge in complexity. There exists a stable covalent chemical bond between monomers that sets apart polymerization from other processes. Polymerization is generally classified into step-growth and chain polymerization. Polymers are categorized into linear polymer and cross-linked polymers that are produced either by condensation or additional polymerization.

Question

2) Write the major products A- P for each of the following reactions. (70 point)
HBr
CH,CH,OK*
CH;CH,OH
t-BuO'K
a)
Br
t-BUOH
Br,/ H20
F
Br
KMNO/ OH
Zn
1) 0,
2) Zn/ CH;COOH
b)
Br
NANH,
CH,CH,I
H.
Li NH;
-78°C
d) A
concd. H,SO,
L.
H,O/ H
Br, CCl,
excess NaNH,
hear
NH,

Expert Solution

This question has been solved!

Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.

SEE SOLUTION Check out a sample Q&A here

Step 1

VIEW

Step 2

VIEW

Step by step

Solved in 2 steps with 2 images

SEE SOLUTION Check out a sample Q&A here

Knowledge Booster

Learn more about

Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.

Similar questions

Orgonic Chemistry II: The answer is writtten as followed. But I Need Explanation. My question is that: Can I siwtch reagent 2 to reagent 1? for example reagent 1 is Cl2,Fecl3, can I changed it to reagent 2??? Why and why not???
Really hoping for solutions since I’m having a hard time with this. Pls. skip if unsure or not willing to answer the subitems (these are all connected for one item). Thanks in advanced. A kin‎etics experi‎ment was p‎erformed for the f‎ormation of a no‎vel comp‎ound, UNO, f‎rom its react‎ants, Ch‎emicals G, R, A, D, and E. Th‎e first six ru‎ns (Runs 1-6) w‎ere all perfor‎med at 301 K, w‎hile the next two ru‎ns (Runs 7-8) at vary‎ing temperatures. Th‎ese are tab‎ulated in the table sho‎wn below. Table 1. Reaction rate for the reaction of the different chemicals at a given concentration at 301 K. Run [G], M [R], M [A], M [D], M [E], M Rate, M/s 1 0.80 0.01 0.20 0.50 2.00 0.180 2 0.80 0.02 0.20 0.50 0.02 3.54 x 10-3 3 0.80 0.01 0.20 0.50 0.02 1.80 x 10-3 4 0.80 0.01 0.60 0.50 0.02 1.80 x 10-3 5 1.20 0.01 0.20 0.50 0.02 4.02 x 10-3 6 0.80 0.01 0.20 0.15 0.02 1.95 x 10-2 a. Calcul‎ate the ra‎te or‎der of e‎ach chem‎ical and over‎all r‎ate or‎der of the…
How would you simplify the following expression?
In light of your answer to Problem 30-40, explain why a mixture of products occurs in the following reaction:
( do 6 with mechanism plz give complete
Can we make S.S.A for I2 -- 2I reaction?
Please give major products im pretty sure the first one is no reaction but I wanted to verify both reactions
This last part didnt post! But I was wondering, for your #6, how do both cls leave?
( give mechanism of 1 and 2
Why does the final product has the opposite configuration compared to the reactant? Shouldn’t it form OMs first, then OMs gets substituted by Cl- via Sn2 (the 1st inversion of configuration) then the Cl- gets substituted by OCH3- (the 2nd inversion of configuration? To my understanding 2 inversions = same configuration
Calculate ▲S°rxn for the following reaction. the S° for each species is shown below in the reaction
Provide a reasonable mechanism for 1(b)