2. In ordering boiling points, you would likely state, correctly, that, given constant carbon chain length, alkanes have the lowest boiling point, with amines a little higher, and alcohols much higher still. Considering that, for constant R-group, amines and alcohols have pretty much the same molar mass, then why should alcohols, with their O, have higher boiling pints than amines, with their N? Just using class discussions, what is different between them such that their physical properties are so different?

2. In ordering boiling points, you would likely state, correctly, that, given constant carbon chain length, alkanes have the lowest boiling point, with amines a little higher, and alcohols much higher still. Considering that, for constant R-group, amines and alcohols have pretty much the same molar mass, then why should alcohols, with their O, have higher boiling pints than amines, with their N? Just using class discussions, what is different between them such that their physical properties are so different?

Organic Chemistry

8th Edition

ISBN:9781305580350

Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote

Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote

Chapter23: Amines

Section: Chapter Questions

Problem 23.22P

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