2. Substances that contain hydrogen carbonate ions (HCO3") always form soluble compounds. This implies that the 1) energy needed to break apart the ionic solid is less than other substances. 2) covalent bonds are greater in the ammonium compound compared to other substances. 3) energy needed to break apart the ionic solid is greater than other substances. 4) covalent bonds are weaker in the ammonium compound compared to other substances

2. Substances that contain hydrogen carbonate ions (HCO3") always form soluble compounds. This implies that the 1) energy needed to break apart the ionic solid is less than other substances. 2) covalent bonds are greater in the ammonium compound compared to other substances. 3) energy needed to break apart the ionic solid is greater than other substances. 4) covalent bonds are weaker in the ammonium compound compared to other substances

Macroscale and Microscale Organic Experiments

7th Edition

ISBN:9781305577190

Author:Kenneth L. Williamson, Katherine M. Masters

Publisher:Kenneth L. Williamson, Katherine M. Masters

Chapter6: Steam Distillation, Vacuum Distillation, And Sublimation

Section: Chapter Questions

Problem 6Q: A mixture of toluene (bp110.8C) and water is steam distilled. Visual inspection of the distillate...

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A 2.00-g sample of a large biomolecule was dissolved in 15.0 g carbon tetrachloride. The boiling point of this solution was determined to be 77 .85C. Calculate the molar mass of the biomolecule. For carbon tetrachloride, the boiling-point constant is 5.03C kg/mol, and the boiling point of pure carbon tetrachloride is 76.50C.
In some regions of the southwest United States, the water is very hard. For example, in Las Cruces, New Mexico, the tap water contains about 560 g of dissolved solids per milliliter. Reverse osmosis units are marketed in this area to soften water. A typical unit exerts a pressure of 8.0 atm and can produce 45 L water per day. a. Assuming all of the dissolved solids are MgCO3 and assuming a temperature of 27C, what total volume of water must be processed to produce 45 L pure water? b. Would the same system work for purifying seawater? (Assume seawater is 0.60 M NaCl.)
A sucrose (C12H22O11) solution that is 45.0% sucrose by mass has a density of 1.203 g/mL at 25C. Calculate its (a) molarity. (b) molality. (c) vapor pressure(vpH2Oat25C=23.76mmHg). (d) normal boiling point.
Acetylene can be made by reacting calcium carbide with water. CaC2(s) + 2 H2O() C2H2(g) + Ca(OH)2(aq) Assume that you place 2.65 g CaC2 in excess water and collect the acetylene over water. The volume of the acetylene and water vapor is 795 mL at 25.0 C and a barometric pressure of 735.2 mmHg. Calculate the percent yield of acetylene. The vapor pressure of water at 25 C is 23.8 mmHg.
Consider two hypothetical pure substances, AB(s) and XY(s). When equal molar amounts of these substances are placed in separate 500-mL samples of water, they undergo the following reactions: AB(s)A+(aq)+B(aq)XY(s)XY(aq) a Which solution would you expect to have the lower boiling point? Why? b Would you expect the vapor pressures of the two solutions to be equal? If not, which one would you expect to have the higher vapor pressure? c Describe a procedure that would make the two solutions have the same boiling point. d If you took 250 mL of the AB(aq) solution prepared above, would it have the same boiling point as the original solution? Be sure to explain your answer. e The container of XY(aq) is left out on the bench top for several days, which allows some of the water to evaporate from the solution. How would the melting point of this solution compare to the melting point of the original solution?
A mixture of toluene (bp110.8C) and water is steam distilled. Visual inspection of the distillate reveals that there is a greater volume of toluene than water present, yet water (bp100C) has the higher vapor pressure. Explain this observation.
When a doughnut is placed on a napkin, the napkin will often absorb a liquid and appear moist. What is most likely the nature of the liquid?
Which of the following will have the lowest total vapor pressure at 25C? a. pure water (vapor pressure = 23.8 torr at 25C) b. a solution of glucose in water with C6H12O6=0.01 c. a solution of sodium chloride in water with NaCl = 0.01 d. a solution of methanol in water with CH3OH=0.2 (Consider the vapor pressure of both methanol [143 torr at 25C] and water.)
Sketch a qualitative graph of the pressure versus time for water vapor above a sample of pure water and a sugar solution, as the liquids evaporate to half their original volume.
When KNO3 is dissolved in water, the resulting solution is significantly colder than the water was originally. (a) Is the dissolution of KNO3 an endothermic or an exothermic process? (b) What conclusions can you draw about the intermolecular attractions involved in the process? (c) Is the resulting solution an ideal solution?

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