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Chemistry: Principles and Practice

Chemistry: Principles and Practice

3rd Edition

ISBN:9780534420123

Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer

Publisher:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer

Chapter9: Chemical Bonds

Section: Chapter Questions

Problem 9.32QE

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Question

Rank the following compounds from smallest to largest lattice energy. (Lowest to highest melting point.)
Сао, Csl, BaS, NaF, NaCl

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Arrange the following series of compounds in order of increasing lattice energies. (a) NaBr, NaCl, KBr (b) MgO, CaO, CaCl2 (c) LiF, BeF2, BeO
What main factors control the magnitude of lattice energies? Give a specific example of a compound that should have a high lattice energy, and explain why its lattice energy is high.
In general the higher the charge on the ions in an ionic compound, the more favorable the lattice energy. Why do some stable ionic compounds have +1 charged ions even though +4, + 5, and +6 charged ions would have a more favorable lattice energy?
The lattice energy of KF is 794 kJ/mol, and the interionic distance is 269 pm. The Na—F distance in NaF, which has the same structure as KF, is 231 pm. Which of the following values is the closest approximation of the lattice energy of NaF: 682 kJ/mol, 794 kJ/mol, 924 kJ/mol, 1588 kJ/mol, or 3175 kJ/mol? Explain your answer.
hat is the enthalpy change for a process? Is enthalpy a state function? In what experimental apparatus are enthalpy changes measured?
For each of the following, write an equation that corresponds to the energy given. a. lattice energy of NaCl b. lattice energy of NH4Br c. lattice energy of MgS d. O9O double bond energy beginning with O2(g) as a reactant
hat does temperature measure? Are the molecules in a beaker of warm water moving at the same speed as the molecules in a beaker of cold water? Explain? What is heat? Is heat the same as temperature?
Compare your answers from parts a and b of Exercise 69 of Chapter 3 with H values calculated for each reaction using standard enthalpies of formation in Appendix 4. Do enthalpy changes calculated from bond energies give a reasonable estimate of the actual values?
The lattice energy of LiF is 1023 kJ/mol, and the LiF distance is 201 pm. MgO crystallizes in the same structure as LiF but with a Mg—O distance of 205 pm. Which of the following values most closely approximates the lattice energy of MgO: 256 kJ/mol, 512 kJ/mol, 1023 kJ/mol, 2046 kJ/mol, or 4008 kJ/mol? Explain your choice.
7.74 In a lattice, a positive ion is often surrounded by eight negative ions. We might reason, therefore, that the lattice energy should be related to eight times the potential of interaction between these oppositely charged particles. Why is this reasoning too simpler?
Define the term lattice energy. Why, energetically, do ionic compounds form? Fig. 3-8 illustrates the energy changes involved in the formation of MgO(s) and NaF(s). Why is the lattice energy of MgO(s) so different from that of NaF(s)? The magnesium oxide is composed of Mg2+ and O2 ions. Energetically, why does Mg2+O2 form and not Mg+O? Why doesnt Mg3+O3 form?
Which compound in each of the following pairs of ionic substances has the most negative lattice energy? Justify your answers. a. LiF, CsF b. NaBr, NaI c. BaCl2, BaO d. Na2SO4, CaSO4 e. KF, K2O f. Li2O, Na2S

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