25. If increasing the concentration of either reactant increases the overall rate of reaction, which is the most likely rate law for the reaction shown below? CH₂CH₂Br(aq) + OH-(aq) → CH3CH₂OH(aq) + Br(aq) A) Rate = k[CH₂CH₂Br] [OH-] B) Rate = k[CH3CH₂Br][ OH-]0 C) Rate = k[CH3CH₂Br][OH-] D) Rate = K[CH3CH₂OH] [Br] E) Rate k[CH3CH₂OH][Br] =

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5th Edition
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Author:John W. Moore, Conrad L. Stanitski
Publisher:John W. Moore, Conrad L. Stanitski
Chapter11: Chemical Kinetics: Rates Of Reactions
Section11.2: Effect Of Concentration On Reaction Rate
Problem 11.3PSP
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most likely rate law for the reaction shown below?
25. If increasing the concentration of either reactant increases the overall rate of reaction, which is the
A) Rate = k[CH3CH₂Br] [OH-]
CH3CH₂Br(aq) + OH-(aq) → CH3CH₂OH(aq) + Br(aq)
B) Rate = k[CH3CH₂Br][ OH-]0
C) Rate = k[CH³CH₂Br][OH-]
D) Rate = k[CH3CH₂OH] [Br]
E) Rate = k[CH3CH₂OH][ Br]
26. Why can the initial rate of reaction (the rate of the reaction during the time when the reaction first
takes place) be used to determine the rate law of a reaction?
A) At the beginning of the reaction, the reactants are at their highest concentration and monitoring the rate
of the reaction when initial concentrations are changed provides information about how each reactant
impacts the rate.
B) At the beginning of the reaction, the reaction is at its slowest point, and therefore this provides
information about how the reactants are interacting with each other in the reaction.
C) At the beginning of the reaction, the reactants behave as catalysts and can lower the activation energy
of the reaction.
27. Which of the following statements regarding catalysts is true?
A) By lowering the activation energy of the reactants, catalysts can increase the rate of reaction.
B) Catalysts can make a reaction more spontaneous by making the enthalpy more exothermic.
C) Adding a catalyst to a reaction increases the concentration of the reactants.
D) A and B are correct
E) A, B, and C are correct
28. The decomposition of hydrogen peroxide is shown below. If the first order time-integrated rate
constant for this reaction is 3.21 x 105 sec¹, how long will it take for half of the initial hydrogen peroxide
to decompose?
2H₂O2(1)→ 2H₂O(1) + O₂(g)
A) 11.3 seconds
B) 1.45 x 10² seconds.
C) 3.21 x 10³ seconds.
D) 2.16 x 104 seconds.
29. If a reactant is observed to be zero order in a reaction, which of the following statements is true? (hint:
write the rate law with a reactant having a 0 reaction order; what would this mean mathematically?)
A) That reactant must be a spectator and does not participate in the net reaction.
B) That reactant must decompose first prior to reacting with the other reactant.
C) That reactant participates in the net reaction, but it does not participate in the rate determining step of
the reaction.
30. If the gauge pressure of a football is 12.5 psi, how many moles of air must be in the football (assume
the football volume is 4.60 L and the temperature of the ball = 25.0 °C; assume the atmospheric pressure
is 1.00 atm; 1 atm = 14.7 psi)
A) 0.348 moles B) 1.00 moles C) 2.88 moles D) 4.44 moles
阿
Nam
L
Transcribed Image Text:most likely rate law for the reaction shown below? 25. If increasing the concentration of either reactant increases the overall rate of reaction, which is the A) Rate = k[CH3CH₂Br] [OH-] CH3CH₂Br(aq) + OH-(aq) → CH3CH₂OH(aq) + Br(aq) B) Rate = k[CH3CH₂Br][ OH-]0 C) Rate = k[CH³CH₂Br][OH-] D) Rate = k[CH3CH₂OH] [Br] E) Rate = k[CH3CH₂OH][ Br] 26. Why can the initial rate of reaction (the rate of the reaction during the time when the reaction first takes place) be used to determine the rate law of a reaction? A) At the beginning of the reaction, the reactants are at their highest concentration and monitoring the rate of the reaction when initial concentrations are changed provides information about how each reactant impacts the rate. B) At the beginning of the reaction, the reaction is at its slowest point, and therefore this provides information about how the reactants are interacting with each other in the reaction. C) At the beginning of the reaction, the reactants behave as catalysts and can lower the activation energy of the reaction. 27. Which of the following statements regarding catalysts is true? A) By lowering the activation energy of the reactants, catalysts can increase the rate of reaction. B) Catalysts can make a reaction more spontaneous by making the enthalpy more exothermic. C) Adding a catalyst to a reaction increases the concentration of the reactants. D) A and B are correct E) A, B, and C are correct 28. The decomposition of hydrogen peroxide is shown below. If the first order time-integrated rate constant for this reaction is 3.21 x 105 sec¹, how long will it take for half of the initial hydrogen peroxide to decompose? 2H₂O2(1)→ 2H₂O(1) + O₂(g) A) 11.3 seconds B) 1.45 x 10² seconds. C) 3.21 x 10³ seconds. D) 2.16 x 104 seconds. 29. If a reactant is observed to be zero order in a reaction, which of the following statements is true? (hint: write the rate law with a reactant having a 0 reaction order; what would this mean mathematically?) A) That reactant must be a spectator and does not participate in the net reaction. B) That reactant must decompose first prior to reacting with the other reactant. C) That reactant participates in the net reaction, but it does not participate in the rate determining step of the reaction. 30. If the gauge pressure of a football is 12.5 psi, how many moles of air must be in the football (assume the football volume is 4.60 L and the temperature of the ball = 25.0 °C; assume the atmospheric pressure is 1.00 atm; 1 atm = 14.7 psi) A) 0.348 moles B) 1.00 moles C) 2.88 moles D) 4.44 moles 阿 Nam L
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