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- Using the following data to calculate Ksp for PbSO4. ε° PbO2 + 4H+ + SO42- + 2e-→ PbSO4(s) + 2H2O +1.69 PbO2 + 4H+ + 2e-→ Pb2+ + 2H2O +1.46 (Hint: Write the general reaction for PbSO4) a. 1.7 × 10-8 b. 5.9 × 107 c. 2.5 × 10-107 d. 4.0 × 10106 e. 3.4 × 10-18Determine the overall rate law and value of k using the following experimental data for the base hydrolysis of ethyl acetate. Trial NaOH CH3COOC2H5 Initial Conductivity of NaOH solution (μs/cm) Initial Rate ((μS/cm)/s)(absolute value) 1 0.0040 M 0.0040 M 985 7.36 2 0.0080 M 0.0040 M 1822 14.74 3 0.0040 M 0.0080 M 936 6.60What is the rate of disapperance of A if the rate of consumption of A is 2.3 x 10^-3 m/s?
- If a mixture was prepared by diluting 7.0 mL of the Blue#1 solution with water to a final volume of 10.0 mL and mixing this with 2.0 mL of diluted bleach how many seconds would it require for the mixture to have an absorbance of 0.120? Use your measured values of b and of the average rate constant, k’ to answer this question. Show all work. Pls help me out asap!!Instantaneous rates for the reaction of hydroxide ion with Cv+ can be determined from the slope of the curve in Figure 11.3 at various concentrations. They are (1) At 4.0 105 mol/L, rate = 12.3 107 mol L1 s1 (2) At 3.0 105 mol/L, rate = 9.25 107 mol L1 s1 (3) At 2.0 105 mol/L, rate = 6.16 107 mol L1 s1 (4) At 1.5 105 mol/L, rate = 4.60 107 mol L1 s1 (5) At 1.0 105 mol/L, rate = 3.09 107 mol L1 s1 (a) What is the relationship between the rates in (1) and (3)? Between (2) and (4)? Between (3) and (5)? (b) What is the relationship between the concentrations in each of these cases? (c) Is the rate of the reaction proportional to the concentration of Cv+? Explain your answer.SAMPLE T - initial T - final Duration of Reaction Color of mixture n-hexane 12:23 30 min orange 2,2,4-trimethylpentane 12:30 13:39 9 s Transparent Benzene 12:37 30 min orange Toluene 12:45 13:40 5 s Transparent 6. Based on the results in Table 5, arrange the hydrocarbons tested in order of decreasing reactivity toward light catalyzed bromination. Give the theoretical explanation for this order in terms of the stability of the corresponding free radicals.
- Rate = -(Delta[RCl])/Delta t andln[RCl]t=-k*t+ln[RCl]0 < [R-Cl]-time equation Test tube A = 0.30 of 0.10M NaOH(aq), 6.70ml DI H2O & 1 drop of bromophenol bue Test Tube B = 3.00M of 0.10M R-CL in acetone. Mix together in 3 water baths Bath A Trial 1= 20C, 53.6s Trial 2= 20C, 49s for color to changeBath B Trial 1= 32C, 18s Trail 2= 32C, 20s Bath C Trial 1= 10C, 204s Trial B= 10C, 200sQ.6 Rearrange the Arrhenius equation into a linear form relating k and TQ.6a To determine Ea, a graph of (xaxis) ____ (in units of ___) vs. (yaxis) ____ needs to be made. This will yioeld a _____ line with a slope = ____ Q.6b enter values used in the table Q.6c Determine the exp. values of Ea with correct sig figs and unitsneed help with this ASAP pls & thank you! (it's asking for you to fill in the blank boxes)( plz asap within 5 min....plz dont answer after 9.00 PM ..i will write plagarism if u answer after 9.00 pm
- The kinetics of hydrolysis of acetylsalicylic acid (aspirin) under certain conditions of temperature, pH, type of buffer and strength ionic, can be followed by multicomponent spectrophotometry. When performing a calculation of optical constants, the following data were obtained: Solution C. mg/100 mL A in λ (276nm) A in λ (290nm) Ac. acetylsalicylic ( AAS) 0.202 0.102 0.031 Ac. salicylic (AS) 0.198 0.158 0.101 Reaction: AAS + H2O → AS + CH3COOH In a kinetic study, after a certain time, 1 mL of the solution was taken from the reactor and diluted to 10 mL with water. distilled. Then when proceeding to the spectrophotometric measurement, the last solution presented the absorbances of 0.244 and 0.102 for the lengths of 276 and 290 nm respectively. What are the concentrations of ASA and AS in mg/L, at that instant in the reactor? Note: Acetic acid does not absorb at either wavelength.What is the rate law expression for the reaction in sodium hydroxide and ethyl acetate? Trial NaOH CH3COOC2H5 Initial Condcutivity of NaOH Solution (uS/cm) Initial Rate (uS/cm)/s) 1 21 ml 2.1ml 1285 24.72 2 21 ml 2.1ml 2399 50.32 3 21 ml 2.1ml 1262 23.72The Km parameter in the Michaelis-Menton-like formulae can be defined as: a. the rate constants for decomposition of ES divided by the rate constant for decomposition of E b. the concentration of substrate that gives 50% Vmax c. the concentration of products that give constant velocity d. the concentration of substrate corresponding to rate constants for decomposition of ES e. the rate constant for formation of ES divided by the rate constant for formation of product