3.Square planar Ir complexes have been widely studied in organometallic catalysis. Providedthe following isomers answer the following questions:CNCNIrIrCNNCIsomer AIsomer Ba.What is the point group of each isomer?Isomer A:Isomer B:b. Determine the reducible and irreducible representations corresponding to the CN stretchingof Isomer A.С.Determine the reducible and irreducible representations corresponding to the CN stretchingof Isomer B.d. With the information learned from the questions a - c, can these 2 isomers be distinguishedwith IR spectroscopy?

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3. Square planar Ir complexes have been widely studied in organometallic catalysis. Provided the following isomers answer the following questions: CN CN ***...... Cl......... Ir Ir ........ CI 'CN NC CI Isomer A Isomer B а. What is the point group of each isomer? Isomer A: Isomer B:

3. Square planar Ir complexes have been widely studied in organometallic catalysis. Provided the following isomers answer the following questions: CN CN ***...... Cl......... Ir Ir ........ CI 'CN NC CI Isomer A Isomer B а. What is the point group of each isomer? Isomer A: Isomer B:

Physical Chemistry

2nd Edition

ISBN:9781133958437

Author:Ball, David W. (david Warren), BAER, Tomas

Publisher:Ball, David W. (david Warren), BAER, Tomas

Chapter13: Introduction To Symmetry In Quantum Mechanics

Section: Chapter Questions

Problem 13.22E: Figure 13.27 shows the structure of the molecule porphine. Figure 13.27 The structure of porphine....

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3.
Square planar Ir complexes have been widely studied in organometallic catalysis. Provided
the following isomers answer the following questions:
CN
CN
Ir
Ir
CN
NC
Isomer A
Isomer B
a.
What is the point group of each isomer?
Isomer A:
Isomer B:
b. Determine the reducible and irreducible representations corresponding to the CN stretching
of Isomer A.
С.
Determine the reducible and irreducible representations corresponding to the CN stretching
of Isomer B.
d. With the information learned from the questions a - c, can these 2 isomers be distinguished
with IR spectroscopy?

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