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- Structural isomers can have very different point groups. There are three isomers of dichlorobenzene. Identify the point groups of the three isomers.The Cu(H2O)62+ complex has octahedral symmetry. Is a transition from a T2g state to an Eg state allowed if the transition moment operator has a T1u symmetry label?In your own words, explain why an object that has more symmetry elements is said to have higher symmetry than an object with fewer symmetry elements.
- Figure 13.27 shows the structure of the molecule porphine. Figure 13.27 The structure of porphine. Determine the symmetry elements present in the molecule, and its point group. Does the point group change if an Fe2+ ion is substituted for the two hydrogen atoms in the center of the porphine ring?Determine the point groups of the following molecules. a Fe(CO)5, which has a trigonal bipyramidal structure, b CO32, which has three resonance structures that contribute to its overall shape, c The perfectly staggered conformation of ethane, d The perfectly eclipsed conformer of ethane.Can you tell me the point group of the following Complex.
- Predict the multiplicities and draw the corresponding tree diagramsWhat point group is produced if an octahedral (Oh) complex is distorted by stretching two trans M-L bonds and compressing another two trans bonds? D4h D2d D2h C4vFind the point groups of all the possible geometrical isomers for the complex MA2B2C2 in which there is ‘octahedral’ coordination around the central atom M and where the ligands A, B, and C are treated as structureless points. Which of the isomers are chiral?