Consider the four sigma bonds of the square planar [P:CI,? complex. If the molecule is on the xy plane and thecolinear Cl-Pt-CI bonds contain the C2: Cz" bisects the Cl-Pt-CI bond angle: , cuts through the colinear Cl-Pt-CIbonds: and a bisects the Cl-Pt-CI bond angle; what is the character of the Calz) operation?Character table for Da point groupE 2C4 (2) C, 20', 20";i 25, 20, 2041111 1-1 -111 1-1-1 1 -1 11 -1linears,quadraticrotationsARx y?-1-1-1xy2 00 20 2 00 (R,. R,) (xz. ya)1111-1 -1 -1 -11-1 -1 -1-1 -111-1 -1 1 -1 -1I 11-11 -0 202 0 0 (x. y)E 2AAzu1-1B21E 2-1-1-2 0O 204---

Solution - The correct option is (d) 4 According to the question - Given - the four sigma bond of…

Consider the four sigma bonds of the square planar (PICP complex. If the molecule is on the xy plane and the colinear Cl-Pt-C bonds contain the C: C;" bisects the C-Pt-Cl bond angle: , cuts through the colinear Cl-Pt-a bonds: and bisects the C-Pt-CI bond angle: what is the character of the Cala) operation? Character table for De point group E 2C, c 20 2c", 25, 20, 20. linears, quadratic rotations Pey", A 1 1 -1 |-1||14 -1 B xy 200 2 0 200 R,.R,) (xz. yz) A A -1 E 2 -2 0 0 2 0 20 (x, y)

Consider the four sigma bonds of the square planar (PICP complex. If the molecule is on the xy plane and the colinear Cl-Pt-C bonds contain the C: C;" bisects the C-Pt-Cl bond angle: , cuts through the colinear Cl-Pt-a bonds: and bisects the C-Pt-CI bond angle: what is the character of the Cala) operation? Character table for De point group E 2C, c 20 2c", 25, 20, 20. linears, quadratic rotations Pey", A 1 1 -1 |-1||14 -1 B xy 200 2 0 200 R,.R,) (xz. yz) A A -1 E 2 -2 0 0 2 0 20 (x, y)

Principles of Modern Chemistry

8th Edition

ISBN:9781305079113

Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler

Publisher:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler

Chapter6: Quantum Mechanics And Molecular Structure

Section: Chapter Questions

Problem 65AP: (a) Sketch the occupied MOs of the valence shell for the N2 molecule. Label the orbitals as or ...

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