One of the more striking hydride complexes is enneahye tricapped trigonal-pyramidal geometry. What is the point group of this ion? Construct a representation using the hydrogen orbitals as a basis. Reduce this to its component irreducible representations, and determine which orbitals of Re are of suitable symmetry to interact with the hydrogen group orbitals.

Physical Chemistry
2nd Edition
ISBN:9781133958437
Author:Ball, David W. (david Warren), BAER, Tomas
Publisher:Ball, David W. (david Warren), BAER, Tomas
Chapter13: Introduction To Symmetry In Quantum Mechanics
Section: Chapter Questions
Problem 13.72E
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One of the more striking hydride complexes is enneahydridorhenate, [ReH], which has
tricapped trigonal-pyramidal geometry. What is the point group of this ion? Construct a
representation using the hydrogen orbitals as a basis. Reduce this to its component
irreducible representations, and determine which orbitals of Re are of suitable symmetry to
interact with the hydrogen group orbitals.
Transcribed Image Text:One of the more striking hydride complexes is enneahydridorhenate, [ReH], which has tricapped trigonal-pyramidal geometry. What is the point group of this ion? Construct a representation using the hydrogen orbitals as a basis. Reduce this to its component irreducible representations, and determine which orbitals of Re are of suitable symmetry to interact with the hydrogen group orbitals.
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ISBN:
9781133958437
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Ball, David W. (david Warren), BAER, Tomas
Publisher:
Wadsworth Cengage Learning,