3. The following mechanism is proposed for the reaction of chlorine with chloroform: Cl, + CHCI, → CC, + HCI Step I fast equilibrium Cl,201 CHCI, +CI- HCI +CCI, CCI, +Cl-»CI, Step 2 slow Step 3 fast a) Show that this mechanism gives the correct, overall balanced reaction equation. b) Write the rate law predicted by this mechanism.

Chemistry & Chemical Reactivity
10th Edition
ISBN:9781337399074
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Chapter14: Chemical Kinetics: The Rates Of Chemical Reactions
Section14.7: Reaction Mechanisms
Problem 14.14CYU: One possible mechanism for the decomposition of nitryl chloride, NO2CI, is What is the overall...
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3. The following mechanism is proposed for the reaction of chlorine with chloroform:
Cl, + CHCI, CCI, + HCI
Cl,
Step 1 fast equilibrium
2Cl
CHCI, +CI » HCI +CCI,
CCI, +Cl»cCI,
Step 2 slow
Step 3 fast
a) Show that this mechanism gives the correct, overall balanced reaction equation.
b) Write the rate law predicted by this mechanism.
Transcribed Image Text:3. The following mechanism is proposed for the reaction of chlorine with chloroform: Cl, + CHCI, CCI, + HCI Cl, Step 1 fast equilibrium 2Cl CHCI, +CI » HCI +CCI, CCI, +Cl»cCI, Step 2 slow Step 3 fast a) Show that this mechanism gives the correct, overall balanced reaction equation. b) Write the rate law predicted by this mechanism.
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