32. Refer to the attached photo. Appendix B Selected Thermodynamic ValuesAH; (298.15 K)(kd/mol)5 (298.15 K)OK mol)AG (298.15 K)(k3/mol)SpeciesCalciumCa(s)41.42Ca(g)178.2158.884144.3Ca?+(g)1925.9Ca+ (aq)542.8353.1-553.58CaC,(s)59.869.96-64.9CaCO,(s, calcite)-1206.9292.9-1128.79CaCl,(s)-795.8104.6-748.1CaF,(s)-1219.668.871167.3CaH,(s)-186.242-147.2CaO(s)-635.0939.75604.03CaS(s)-482.456.5477.4Ca(OH),(s)986.0983.39-898.49Ca(OH),(aq)-1002.82-74.5-868.07CaSo,(s)-1434.11106.7-1321.79CarbonC(s, graphite)C(s, diamond)5.740.1.8952.3772.9C(g)716.682158.096671.257,(CCIA(Cי-135.44216.4-65.21-102.9309.85-60.59CCl,(g)CHCI,()-134.47201.7-73.66295.71-70.34CHCI, (g)-103.14CH, (g, methane)-74.81186.264-50.72C,H, (g, ethyne)226.73200.94209.2C,H, (g, ethene)52.26219.5668.15C,H, (g, ethane)-84.68229.6-32.82269.9-23.49C,H3 (g, propane)C,Ho (g, butane)CH(C, benzene)-103.8-126.148310.227-16.98549.03172.8124.5CH14(e, hexane)296.0184.035198.78216.718CaH18 (g, octane)CHjg(C, octane)CH,OH(E, methanol)-208.447466.835-249.952361.2056.707-238.66126.8-166.27CH,OH(g, methanol)-200.66239.81-161.96CH;OH(aq, methanol)-245.931133.1175.31C,H,OH(C, ethanol)-277.69160.7-174.78CH,OH(g, ethanol)-235.1282.7-168.49C,H,OH(aq, ethanol)-288.3148.5-181.64 32. It would be very useful if we could use the inexpensive carbon in coal to make more complex organic molecules such asgaseous or liquid fuels. The formation of methane from coal and water is reactant-favored and thus canmot occur unlessthere is some energy transfer from outside. This problem examines the feasibility of other reactions using coal andwater.a) Write three balanced equations for the reactions of coal (carbon) and steam to make ethane gas, C,H,(g), propanegas, C3H3(g), and liquid methanol, CH;OH(), with carbon dioxide as a by-product.b) Using the data in Appendix B, calculate AH°, AS°, and AG° for each reaction, and then comment on whether any ofthem would be a feasible way to make the stated products.

a) the Balanced reaction are 1. 2C(s) + 3H2(g) → C2H6(g) 2. 3C(s) + 4H2(g) → C3H8(g)…

32. It would be very useful if we could use the inexpensive carbon in coal to make more complex organic molecules such as gaseous or liquid fuels. The formation of methane from coal and water is reactant-favored and thus canmot occur unless there is some energy transfer from outside. This problem examines the feasibility of other reactions using coal and water. a) Write three balanced equations for the reactions of coal (carbon) and steam to make ethane gas, C2H(g), propane gas, C,Hs(g), and liquid methanol, CH;OH((), with carbon dioxide as a by-product. b) Using the data in Appendix B, calculate AH°, AS°, and AG° for each reaction, and then comment on whether any of them would be a feasible way to make the stated products.

32. It would be very useful if we could use the inexpensive carbon in coal to make more complex organic molecules such as gaseous or liquid fuels. The formation of methane from coal and water is reactant-favored and thus canmot occur unless there is some energy transfer from outside. This problem examines the feasibility of other reactions using coal and water. a) Write three balanced equations for the reactions of coal (carbon) and steam to make ethane gas, C2H(g), propane gas, C,Hs(g), and liquid methanol, CH;OH((), with carbon dioxide as a by-product. b) Using the data in Appendix B, calculate AH°, AS°, and AG° for each reaction, and then comment on whether any of them would be a feasible way to make the stated products.

Chemistry for Engineering Students

3rd Edition

ISBN:9781285199023

Author:Lawrence S. Brown, Tom Holme

Publisher:Lawrence S. Brown, Tom Holme

Chapter10: Entropy And The Second Law Of Thermodynamics

Section: Chapter Questions

Problem 10.39PAE: How does the second law of thermodynamics explain a spontaneous change in a system that becomes more...

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