4) The plot below shows the trend in orbital energies for 1s, 2s, 2p, 3s, and 3p orbitals. A more negative potential energy corresponds to a more stable electron in that orbital. Explain the general reasoning behind each of the following trends or observations briefly. Na a Mgo Si Al В 3p -10 2P Şi 1s -20 He 25 Не 3s CI -30 -40 -50 + 10 15 20 Atomic number Miessler, Fischer & Tarr. Inorganic Chemistry 5th Edition. a) For the same value of n and I quantum numbers, an orbital is stabilized by moving to the right of the periodic table (e.g. B →C→N→O...) b) The trend you just described in question part a) has a larger effect on the 2s series than on the 2p series. Potential energy (eV)

Principles of Modern Chemistry
8th Edition
ISBN:9781305079113
Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Chapter6: Quantum Mechanics And Molecular Structure
Section: Chapter Questions
Problem 26P: Following the pattern of Figure 6.21, work out the correlation diagram for the BeN molecule, showing...
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4) The plot below shows the trend in orbital energies for 1s, 2s, 2p, 3s, and 3p orbitals.
A more negative potential energy corresponds to a more stable electron in that
orbital. Explain the general reasoning behind each of the following trends or
observations briefly.
3p
-10
1s
-20
He
25
35
-30
-40
-50
10
15
20
Atomic number
Miessler, Fischer & Tarr. Inorganic Chemistry 5th Edition.
a) For the same value of n and I quantum numbers, an orbital is stabilized by moving
to the right of the periodic table (e.g. B → C →N→ 0...)
b) The trend you just described in question part a) has a larger effect on the 2s series
than on the 2p series.
Potential energ
energy (eV)
Transcribed Image Text:4) The plot below shows the trend in orbital energies for 1s, 2s, 2p, 3s, and 3p orbitals. A more negative potential energy corresponds to a more stable electron in that orbital. Explain the general reasoning behind each of the following trends or observations briefly. 3p -10 1s -20 He 25 35 -30 -40 -50 10 15 20 Atomic number Miessler, Fischer & Tarr. Inorganic Chemistry 5th Edition. a) For the same value of n and I quantum numbers, an orbital is stabilized by moving to the right of the periodic table (e.g. B → C →N→ 0...) b) The trend you just described in question part a) has a larger effect on the 2s series than on the 2p series. Potential energ energy (eV)
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