4. Carbonate System. An amount of NaHCO, was added to water such that the total carbonate concentration was 104 M. If it is assumed that no other constituents are present, a pC-pH diagram for this water-carbonate system is shown below. (a) What is the statement of mass balance for total dissolved carbonate in the system? (b) What is the charge balance for dissolved species in the system? (c) What is the proton condition for this system if NaHCO; was added to water? (d) Using the diagram and the proton condition for this system, what is the equilibrium pH? (e) What is the equilibrium solution condition indicated by the left vertical dashed line at pH =

4. Carbonate System. An amount of NaHCO, was added to water such that the total carbonate concentration was 104 M. If it is assumed that no other constituents are present, a pC-pH diagram for this water-carbonate system is shown below. (a) What is the statement of mass balance for total dissolved carbonate in the system? (b) What is the charge balance for dissolved species in the system? (c) What is the proton condition for this system if NaHCO; was added to water? (d) Using the diagram and the proton condition for this system, what is the equilibrium pH? (e) What is the equilibrium solution condition indicated by the left vertical dashed line at pH =

Principles of Modern Chemistry

8th Edition

ISBN:9781305079113

Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler

Publisher:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler

Chapter16: Solubility And Precipitation Equilibria

Section: Chapter Questions

Problem 52P

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xpress numerical result with an accuracy of: Х,Х 1. The substance to be analyzed – is deep-pink colored, highly soluble in water salt. Reaction with NH3 gives blue-colored precipitate, which can be dissolved in NH3 surplus accompanied by dirty-yellow colored solution formation. After precipitation of cation by “sodium carbonate drawing out” method, supernatant was independently treated by silver nitrate solution and barium chloride solution (in acid medium in both cases) – any precipitation hasn`t been observed. Addition of antipyrin in acid medium changes color to red. What kind of substance is this? Explain you answer, provide chemical equations
Using basic conditions, MnO4- can be used as titrant for the analysis of Mn2+, with both the analyte and the titrant ending up as MnO2. In the analysis of a mineral sample for manganese, a 0.5165-g sample is dissolved, and the manganese is reduced to Mn2+. The solution is made basic and titrated with 0.03358 M KMnO4, requiring 34.88 mL to reach the endpoint. Calculate the %w/w Mn in the mineral sample. Answer: % Mn =
Which of the following is a good description of a standard solution as a titrant? a) selectively reactive with the analyte b) only reacts with the matrix c) oxidize when exposed to air d) reacts very slowly but completely
The concentration of ammonia in a cleaning product was determined by back titration.Firstly, 10.00 cm3 of the cleaning product was pipetted into a large conical flask,containing 250.00cm3 of 0.50 mol/l HCl to give Solution A.Following a period of reaction and shaking, 50.00cm3 of Solution A was removed anddiluted to 250 cm3 with water in a volumetric flask to give Solution B.20 cm3 samples of Solution B were titrated against 0.05 mol/l Na2CO3 solution, givingan average titre of 12.45 cm3. i) Write equations for the reactions that have taken place.ii) Determine the concentration of NH3 in the original cleaning product in mol/l,g/l, ppm, and % w/v.
A mixture of NaBr, Nal and NaNO3 weighs 0.6500 g. With AgNO3, a precipitate of the two halides is obtained and is found to weigh 0.9390 g. When heated in a current of C2, the precipitate is converted entirely to AgCi weighing 0.6566 g. What is the %NaNO3 in the original sample?
While working in a metal processing facility, Letlen had accidentally mixed two metal vatstogether creating an alloy. One vat was labeled for cadmium, while the other was not. It canbe assumed that these are of pure metal composition. To identify this metal, Letlen took 1.000 g of the homogenous alloy sample composed ofcadmium and the unknown metal, dissolved, and diluted it to exactly 100.0 mL in avolumetric flask. A 20.00-mL aliquot was taken and titrated this using 22.82 mL of 0.05000M EDTA. In a second 20.00-mL aliquot, the Cd was masked through the addition of HCN/NaCN buffer.The titration of the unknown metal in the aliquot required 15.13 mL of EDTA.MW: Cd (112.411 g/mol) a. Calculate the moles of Cd and the moles of unknown metal in the 20.00-mL aliquot.b. Calculate the moles of Cd and the moles of unknown metal in the sample.
True or False: Blank titration is indicated for the determination of the concentration of a sample. Can you please expound why?
In this activity, you will develop an experimental procedure to solve a problem. Consider the followingscenario:You are the manager of a chemical stockroom, and find a bottle containing approximately one liter of aclear and colorless solution of unknown identity and concentration. Your only clue to its identity is thatit was found between bottles of silver fluoride and sodium fluoride, so it is likely an aqueous solution ofone of those two compounds. You will need to develop a procedure to determine the following:a) The identity of the unknown solutionb) The concentration of the unknown solutionWrite out a precise procedure, which includes all glassware, reagents, and steps. You will also need towrite the calculations that you would need to determine the concentration of the solution. Assume thatyou have access to any reagent you might need
Contamination of precipitate by co-precipitation can be minimized by (tick all that may apply) A. Digestion B. Peptization C. Washing D. Re-precipitation
In complexometric titration ‘the reaction with analyte should be rapid andcomplete’ give reason with suitable justification for the above statement.
Volumetric Analysis The mass of KHC8H4O4 is measured to the nearest milligram; however, the volume of water in which it is dissolved is never of concern—water is even added to the wall of the Erlenmeyer flask during the titration. Explain why water added to the KHC8H4O4 has no effect on the data, whereas water added to the NaOH solution, may drastically affect the data.
The level of dissolved oxygen in a water sample can be determined by the Winkler method. In a typical analysis, a 100.0-mL sample is made basic, and treated with a solution of MnSO4, resulting in the formation of MnO2. An excess of KI is added, and the solution is acidified, resulting in the formation of Mn2+ and I2. The liberated I2 is titrated with a solution of 0.00870 M Na2S2O3, requiring 8.90 mL to reach the starch indicator end point. Calculate the concentration of dissolved oxygen as parts per million of O2.