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- Use your knowledge of directing effects, along with the following data, to deduce the directions of the dipole moments in aniline and bromobenzene.Which reagent(s) sequence(s) is/are optimum for preparing butanoic acid from 1-propanol? i. K2Cr2O7 in acidii. (1) PBr3; (2) NaCN; (3) H2O; (4) [H+] iii. (1) NaCN; (2) H2O; (3) [H+]iv. LiAlH4Can you please help show how to appraoch this problem and eleaborate the steps.
- Organotin compounds play a significant role in diverse industrial applications. They have been used as plastic stabilizers and as pesticides or fungicides.One method used to prepare simple tetraalkylstannanes is the controlled direct reaction of liquid tin(IV) chloride with highly reactive trialkylaluminum compounds, such as liquid triethylaluminum (Al(C2H5)3). 3SnCl4 + 4Al(C2H5)3 3Sn(C2H5)4 + 4AlCl3 In one experiment, 0.230 L of SnCl4 (d = 2.226 g/mL) was treated with 0.396 L of triethylaluminum (Al(C2H5)3); d = 0.835 g/mL). If 0.335 L of tetraethylstannane (d = 1.187 g/mL) were actually isolated in this experiment, what was the percent yield?The molecular formula of unknown compound B is C10H16.Quantitative brominationof a 0.473-g sample of compound Brequired 48.22mL of a 0.216MBr2/CCl4to produce a color change. How many rings and pi bonds does compound Bcontain?Include any explanations/calculations to justify your answers.Qn no. 20. Kindly provide proper explanation with all details for each step.
- Propose a suitable mechanism based on the observation .w how enols, enolate ions, andenamines act as nucleophiles. Predictthe products of their reactions withhalogens, alkyl halides, and otherelectrophiles. Show how they areuseful in synthesis.Explain how and why rearrangements occurduring Friedel-Crafts alkylation reactions formingmore than 1 product. Also illustrate therearrangement reaction from the aboveexample.
- Phenols (ArOH) are relatively acidic, and the presence of a substituent group on the aromatic ring has a large effect. The pKa of unsubstituted phenol, for example, is 9.89, while that of p-nitrophenol is 7.15. Draw resonance structures of the corresponding phenoxide anions and explain the data.The following Walden cycle has been carried out. Explain the results, and indicate where Walden inversion occurs.All attempts to isolate primary and secondary nitroso compounds result solely in the formation of oximes. Tertiary nitroso compounds, however, are stable. Explain.