4. Tertiary amines undergo reversible conjugate additions to a ß-unsaturated carbonyls. The reaction shown below uses this phenomenon followed by an aldol-like process to obtain the given product. Show a detailed mechanism for this reaction. The structure of one of the intermediates is shown below to assist in drawing the mechanism он о Ph Ph H20/E1OH Он О intermediate: Ph `NME3

Organic Chemistry: A Guided Inquiry
2nd Edition
ISBN:9780618974122
Author:Andrei Straumanis
Publisher:Andrei Straumanis
Chapter26: Aldol And Claisen Reactions
Section: Chapter Questions
Problem 26E
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4. Tertiary amines undergo reversible conjugate additions to a,ß-unsaturated carbonyls.
The reaction shown below uses this phenomenon followed by an aldol-like process to
obtain the given product. Show a detailed mechanism for this reaction. The structure of
one of the intermediates is shown below to assist in drawing the mechanism
ОН О
Ph
+
Ph
H.
H2O/E1OH
ОН О
intermediate:
Phi
`NMe3
Transcribed Image Text:4. Tertiary amines undergo reversible conjugate additions to a,ß-unsaturated carbonyls. The reaction shown below uses this phenomenon followed by an aldol-like process to obtain the given product. Show a detailed mechanism for this reaction. The structure of one of the intermediates is shown below to assist in drawing the mechanism ОН О Ph + Ph H. H2O/E1OH ОН О intermediate: Phi `NMe3
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