4. The cadmium and lead ions in a 50.00 mL sample required 40.09 mL of a 0.005000 M EDTA for titration. A 75.00 mL portion of the same sample was made basic and treated with excess KCN masking the cadmium as Cd(CN),2. This solution required 21.42 mL of the EDTA for titration. Calculate the concentration of Cd²* and Pb²* in the sample ppm and in M.
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- To analyze the amount of iron (Fe; Mw = 55.85 g/mol) contained in an ore sample, the sample was digested with acid and diluted to 50 mL with water. This solution was then treated with 25.00 mL of 0.2922 M EDTA. The excess EDTA was back titrated with 6.47 mL of 0.0843 M Zn2+ to reach the equivalence point. How many grams of Fe contained in the ore sample?A 0.7352g sample of ore containing Fe3+, Al3+ and Sr2+ was dissolved and made up to 500.00 mL. The analysis of metals was performed by a chemistry using complexation volumetry. Initially, an aliquot of 50.00 mL had its pH adjusted to 1.0 and titrated with a standard solution of EDTA 0.02145 mol/L, requiring 6.95 mL to reach the end point. Subsequently, another 25.00 mL aliquot was buffered at pH=5 and titrated with the same EDTA solution, requiring 6.24 mL to reach the end point. Finally, a third aliquot of 25.00 mL was titrated at pH=11, requiring 11.10 mL of the same EDTA solution to complete the titration. Determine the percentage of each of the metals in the sample Given the molar masses: Fe=55.845 g/mol; Al=26.982 g/mol and Sr=87.620 g/mol.The amount of Fe in a 0.4891 gm sample of an ore was determined by redox titration with K Cr , 0 ,. The sample was dissolved in HCl , and the iron brought into ( +2 ) oxidation state . The titration to the end point required 36.92ml of 0.02153 M K Cr , 0 ,. Report the iron content of the ore as % w / w Fe 03 .
- Chromel is an alloy composed of nickel, iron and chromium.A 0.6472 g sample was dissolved and diluted to 250 mL. When a50 mL aliquot of 0.05182 M EDTA was mixed with an equal volumeof the diluted sample and all the three ions were chelated, a 5.11 mLback titration with 0.06241 M copper (II) was required.The chromium in a second 50 mL aliquot was masked through theaddition of hexamethylenetetramine, titration of the Fe and Nirequired 36.28 mL of 0.05182 M EDTA.Iron and chromium were masked with pyrophosphate in a third50 mL aliquot and the nickel was titrated with 25.91 mL of theEDTA solution.Calculate the percentage of nickel, chromium and iron in thealloy.0.4545 g CaCO3 was dissolved in HCl and the resulting solution was diluted to 0.25 L. Twenty-five mL aliquot of this solution required 35.2 mL of EDTA upon performing titrimetric analysis. Determine the molarity of EDTAThe amount of iron in a meteorite is determined by a redox titration using KMnO4 as the titrant. A 0.4185-g sample is dissolved in acid and the liberated Fe3+ quantitatively reduced to Fe2+ using a Walden reductor. Titrating with 0.02500 M KMnO4 requires 41.27 mL to reach the end point.(a) Determine the %w/w Fe2O3 (MW = 159.69 g/mol) in the sample of meteorite.(b) Determine the %w/w Fe3O4 (MW = 231.533 g/mol) in the sample of meteorite.
- A sample of steel weighing 2.00 g is analyzed for Cr (AW 52.0). The Cr is oxidized into chromate with alkaline permanganate and the excess permanganate is destroyed. A certain volume of 0.120 M FeSO4 is added to the acid solution and the excess is titrated with 0.0220 M KMnO4, requiring 31.0 mL. If the sample contained 0.50 % Cr, what volume (in mL) of FeSO4 was added?In a titration experiment, 25.0 ml of 0.0500M Sn was titrated with 0.10OM Fe in I M HCl to give Fe and Sn', using Pt and calomel electrodes Fe (aq) +e Fe (aq) E" = 0.732 V Sn (aq) +2e Sn E 0.139 V E(calomel) = 0.241VN Calculate E when 28.5mL of Fe is added.0.7120 g of iron ore was dissolved and the iron was reduced to Fe2+ with Jones's reagent. Fe(II) was titrated with 0.02086 M KMnO4 and consumed 39.21 mL. What is the iron content of iron ore? Report the concentration as percentage of iron (Fe%) and iron oxide (Fe2O3%).
- An alloy containing Ni, Fe and Cr was analyzed by a complexation titration using EDTA as titrant. A 0.7176 g sample of the alloy was dissolved in HNO3 and diluted to 250 mL in a flask. A 50.00 mL aliquot of the sample, treated with pyrophosphate to mask Fe and Cr, required 26.14 mL of 0.05831 M EDTA to reach the murexide endpoint. A second 50.00 mL aliquot was treated with hexamethylenetetramine to mask Cr and titration with 0.05831 M EDTA required 35.43 mL to reach the murexide endpoint. Finally, a third 50.00 mL aliquot was treated with 50.00 mL of 0.05831 M EDTA and titrated back to the murexide endpoint with 6.21 mL of 0.06316 M Cu(II). the weight percentages of Ni, Fe and Cr in the alloy.The amount of iron in a meteorite is determined by a redox titration using KMnO4 as the titrant. A 2.1800 g sample is dissolved in acid and the liberated Fe3+ quantitatively reduced to Fe2+ using a Walden reductor. Titrating with 0.02500 M KMnO4 requires 22.0 mL to reach the end point. Determine the %w/w Fe2O3 in the sample of meteorite.A 20 mL volume of 0.015 M KIO3 containing an excess of KI, is added to a 0.312 g sample of a Real Lemon solution containing vitamin C. The Yellow-brown solution, caused by excess I2 is titrated to a colorless starch endpoint with 11.3 mL pf 0.106M Na2S2O3. Question: What is the equation for I- titrated with the IO3 standard solution.