The following measurements were recorded for standard solutions of metal complexes with EDTA using a sample cell with a path length of 1.0 cm. Aqueous Co2+ E379 = 2,616 cm-1M-1 and E463 = 6,459 cm-1M-1 Aqueous Ni2+ E379 = 6,591 cm and E 463 = 2,428 cm-1M-1 Mix of Co2+ and Ni2+ concentration unknown A379 = 0.4533 and A463 = 0.7777 What is the concentration of Ni2+ in the mix?

Fundamentals Of Analytical Chemistry
9th Edition
ISBN:9781285640686
Author:Skoog
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Chapter26: Molecular Absorption Spectrometry
Section: Chapter Questions
Problem 26.17QAP
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The following measurements were recorded for standard solutions of metal complexes with EDTA using a sample cell with a path length of 1.0 cm.
Aqueous Co2+ E379 = 2,616 cm-M-1 and &,
463 = 6,459 cm-M-1
Aqueous Ni2+
379 = 6,591 cm'M' and &463 = 2,428 cmM-1
Mix of Co2+
and Ni2+
concentration unknown A379 = 0.4533 and A463 = 0.7777
What is the concentration of Ni2+ in the mix?
Transcribed Image Text:The following measurements were recorded for standard solutions of metal complexes with EDTA using a sample cell with a path length of 1.0 cm. Aqueous Co2+ E379 = 2,616 cm-M-1 and &, 463 = 6,459 cm-M-1 Aqueous Ni2+ 379 = 6,591 cm'M' and &463 = 2,428 cmM-1 Mix of Co2+ and Ni2+ concentration unknown A379 = 0.4533 and A463 = 0.7777 What is the concentration of Ni2+ in the mix?
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