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4. The reaction: 2 C1O2(aq) + 2 OH(aq) → C103 (aq) + ClO2'(aq) + H2O(1) was studied with the following initial concentrations of reactants at 50°C: Experiment [CIO,] (M) [OH] (M) Initial Rate: (M/s) 1 0.060 0.030 0.0248 0.020 0.030 0.00276 3 0.020 0.090 0.00828 a) Determine the rate law for the reaction. b) Calculate the rate constant, k, for this reaction using the data from each run and then calculate the average value for the rate constant, k. c) Using the average value for the rate constant, calculate the initial rate of the reaction when the initial concentrations of the reactants are [CIO2] = 0.10M and [OH]=0.050M.

4. The reaction: 2 C1O2(aq) + 2 OH(aq) → C103 (aq) + ClO2'(aq) + H2O(1) was studied with the following initial concentrations of reactants at 50°C: Experiment [CIO,] (M) [OH] (M) Initial Rate: (M/s) 1 0.060 0.030 0.0248 0.020 0.030 0.00276 3 0.020 0.090 0.00828 a) Determine the rate law for the reaction. b) Calculate the rate constant, k, for this reaction using the data from each run and then calculate the average value for the rate constant, k. c) Using the average value for the rate constant, calculate the initial rate of the reaction when the initial concentrations of the reactants are [CIO2] = 0.10M and [OH]=0.050M.

Chemistry for Engineering Students
Chemistry for Engineering Students
4th Edition
ISBN:9781337398909
Author:Lawrence S. Brown, Tom Holme
Publisher:Lawrence S. Brown, Tom Holme
Chapter11: Chemical Kinetics
Section: Chapter Questions
Problem 11.36PAE: The reaction NO(g) + O,(g) — NO,(g) + 0(g) plays a role in the formation of nitrogen dioxide in...
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4. The reaction: 2 C102(aq) + 2OH (aq) → ClO3 (aq) + ClO, (aq) + H2O(1) was studied with the following initial concentrations of reactants at 50°C: Experiment [ClO,] (M) [OH] (M) Initial Rate: (M/s) 1 0.060 0.030 0.0248 0.020 0.030 0.00276 3 0.020 0.090 0.00828 a) Determine the rate law for the reaction. b) Calculate the rate constant, k, for this reaction using the data from each run and then calculate the average value for the rate constant, k. c) Using the average value for the rate constant, calculate the initial rate of the reaction when the initial concentrations of the reactants are [CIO2] = 0.10M and [OH]= 0.050M.
Transcribed Image Text:4. The reaction: 2 C102(aq) + 2OH (aq) → ClO3 (aq) + ClO, (aq) + H2O(1) was studied with the following initial concentrations of reactants at 50°C: Experiment [ClO,] (M) [OH] (M) Initial Rate: (M/s) 1 0.060 0.030 0.0248 0.020 0.030 0.00276 3 0.020 0.090 0.00828 a) Determine the rate law for the reaction. b) Calculate the rate constant, k, for this reaction using the data from each run and then calculate the average value for the rate constant, k. c) Using the average value for the rate constant, calculate the initial rate of the reaction when the initial concentrations of the reactants are [CIO2] = 0.10M and [OH]= 0.050M.
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