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- 5.Measures to observe when measuring viscous liquids include the following, with exception ofa.Use of silicone treated glassware for smaller volume of liquidsb.Pouring from bottle that is not completely filledc.When pouring, do not allow the liquid to run down the inside surface of the graduatesd.Drainage time is longer6.Most accurate balance to use for pharmaceutical analysisa.Household scaleb.Top loading balancec.Analytical balanceTriple beam balancea concentrated H2SO4 has the following composition specific gravity 1.84 and purity of H2SO4 is 97 percent by weight. express in mole/LOsmotic pressures are often reported in units of atmospheres or mm Hg. The latter impliesthat the height of a column of liquid can be used as a measure of pressure. This is, in fact, thebasis of the torricellian barometer from which the units of “torr” come. The pressure, P, isrelated to the height of the column by:P = ρghwhere ρ is the density of the liquid, g is the acceleration due to gravity and h is the height. Whatwill be the height (in mm) of a column of aqueous solution with a density of 0.9987 g/mL, if theosmotic pressure of the solution at 25 °C is 1.4 mm Hg? The density of mercury at thistemperature is 13.8 g/mL
- The Ogallala aquifer described in the Closer Look box in, provides 82% of the drinking water for thepeople who live in the region, although more than 75% ofthe water that is pumped from it is for irrigation. Irrigationwithdrawals are approximately 18 billion gallons per day.(a) Assuming that 2% of the rainfall that falls on an areaof 600,000 km2 recharges the aquifer, what average annualrainfall would be required to replace the water removed forirrigation? (b) What process or processes accounts for thepresence of arsenic in well water?Crude petroleum is formed from organic matter that accumulates in sea basins and estuaries and decomposed by anaerobic bacteria resulting to a black viscous product. A typical elemental analysis shows 81% C, 13%H, 1%N, 3% O, and 2% S. During a certain combustion, air is supplied in less than theoretical amount. 75% of the O2 burns up to CO2 and the rest to CO. The molal ratio CO to H2 in the flue gas is 1:2.a. Calculate the Orsat analysis of the flue gas b. % of the theoretical air supplied for combustion c. m3 air supplied/kg cure petroleumAmmonium chloride, NH4Cl, decomposes when it is heated. (a) How many components and phases are present when the salt is heated in an otherwise empty container? (b) Now suppose that additional ammonia is also present. How many components and phases are present?
- 6.A fuel is burned with 50% excess air and the combustion characteristics of the fuel oil are similar to C12H26. Determine the ff. a) air fuel ratio b) volumetric (molal) analysis of the products of combustion.Pressure was exerted with a piston on molten naphthalene at 95 °C. The vaporpressure of naphthalene when the applied pressure is 1.0 bar is 2.0 kPa. What is thevapor pressure when the pressure on the liquid is 15 MPa? The mass density ofnaphthalene at this temperature is 1.16 g cm-1.Air at 25 oC , 740 mm Hg and 55% Relative Humidity is compressed to 10 atm. To what temperature (oC) must the air-water mixture be cooled if 90 % of the water is to be condensed ?
- Show calculations for the experimental percentage of water for Trial 1Percentage of Water in Hydrate AverageUsing a methanol-water mixture as a solvent, a supersaturated solution of sodium chloride and sucrose is made in closed container. The system is let to reach equilibrium woth gas and solid phases. Name the phases and components of the system and define the degree of freedom and its meaning.A parcel of unsaturated air contains a mixture of dry air and water vapor. The specific humidity q of the air parcel is 12 g kg^−1. Recall that q = Mv / (Mv+Md),where Mv is the mass of the water vapor and Md is the mass of the dry air. This is equivalent to what we have been calling the fractional concentration of water vapor by mass. (a) If the air parcel is at a temperature T= 25◦C , what is the virtual temperature of the air parcel? (b) If the air parcel is at a temperature T= 25◦C and a pressure of 1000 hPa, what is the relative humidity of the air parcel? (c) What is the apparent molar mass of the air parcel?