5.2 5.0 4.8 4.6 4.4 4.2 4.0 3.8 3.6 160 140 120 100 80 60 40 20 3.4 10,000 20,000 30,000 Time (s) 10,000 30,000 20,000 Time (s) (a) (b) A Figure 14.7 Kinetic data for conversion of methyl isonitrile into acetonitrile. Pressure, CHgNC (torr) In pressure, CH3NC

5.2 5.0 4.8 4.6 4.4 4.2 4.0 3.8 3.6 160 140 120 100 80 60 40 20 3.4 10,000 20,000 30,000 Time (s) 10,000 30,000 20,000 Time (s) (a) (b) A Figure 14.7 Kinetic data for conversion of methyl isonitrile into acetonitrile. Pressure, CHgNC (torr) In pressure, CH3NC

Principles of Modern Chemistry

8th Edition

ISBN:9781305079113

Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler

Publisher:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler

Chapter12: Thermodynamic Processes And Thermochemistry

Section: Chapter Questions

Problem 79AP

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Concept explainers

Repulsive and Total Interactions Between Molecules

Intermolecular forces are the repulsive or attractive interaction between the molecules. Due to the coulomb’s law, there will be a coulomb force that exists between two or more charged species. If the charge of both molecules is positive or negative, then that will lead to repulsive forces. When they have opposite charges, then the force is attractive.

Question

What can you conclude given that the plot of ln P versus t is
linear?

5.2
5.0
4.8
4.6
4.4
4.2
4.0
3.8
3.6
160
140
120
100
80
60
40
20
3.4
10,000
20,000 30,000
Time (s)
10,000
30,000
20,000
Time (s)
(a)
(b)
A Figure 14.7 Kinetic data for conversion of methyl isonitrile into acetonitrile.
Pressure, CHgNC (torr)
In pressure, CH3NC

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