6. The MS andđ 13C NMR spectra for two constitutional İsomers with 4 degrees of unsaturation are shown below. Please determine the molecular structures of the two constitutional isomers. ISOMER A ISOMER B 100 - 100- 80- 80 - 60 60- 40- MTs 140 20- 20- 25 50 100 125 25 100 125 m/z m/z m?patas total -Zpeaks 3 peales tolal 200 180 160 140 120 100 80 60 40 20 200 180 160 140 120 100 80 60 40 20 CoS-00-887 ppm Cos-00-e86 ppm Relative Intensity Relative Intensity

Organic Chemistry: A Guided Inquiry
2nd Edition
ISBN:9780618974122
Author:Andrei Straumanis
Publisher:Andrei Straumanis
ChapterL3: Carbon (13c) Nmr Spectroscopy
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Problem 12CTQ
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6. The MS and 13C NMR spectra for two constitutional Isomers with 4 degrees of unsaturation are shown below. Please determine
the molecular structures of the two constitutional isomers.
ISOMER A
ISOMER B
100 -
100-
80
80 -
60-
60-
40-
MTs 140
20-
20-
25
50
100
125
25
s0
100
125
m/z
m/z
Speales tofat
-Zpeaks
200
180
160
140
120
100
80
60
40
20
200
180
160
140
120
100
80
60
40
20
CoS-00-887
ppm
CoS-00-686
pm
Relative Intensity
Relative Intensity
Transcribed Image Text:6. The MS and 13C NMR spectra for two constitutional Isomers with 4 degrees of unsaturation are shown below. Please determine the molecular structures of the two constitutional isomers. ISOMER A ISOMER B 100 - 100- 80 80 - 60- 60- 40- MTs 140 20- 20- 25 50 100 125 25 s0 100 125 m/z m/z Speales tofat -Zpeaks 200 180 160 140 120 100 80 60 40 20 200 180 160 140 120 100 80 60 40 20 CoS-00-887 ppm CoS-00-686 pm Relative Intensity Relative Intensity
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