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- Arrange the structure on the image with regard to the reactivity towards nucleophilic acyl substitution 1 being the least and 3 being the mostRank A, B, and C in order of increasing SN1 reactivity.If compound 1 is instead reacted with strong aqueous acid a different product is formed, with the formula C12H1O. Identify the product and draw the full curly arrow mechanism for its formation
- Explain how substituents on thearomatic ring promote substitutionat some positions but not at otherswhich newman projection displays the proper antiperiplanar orientation for an E2 elimination of the reaction sequence belowHow would you predict the major organic product formed with the given conditions, when accounting for regiochemistry and stereochemistry (if necessary). If there is more than one stereoisomer product, how would you draw them using the appropriate wedges and dashes?
- A difficult problem in the synthesis of PGF2α is the introduction of the OH group at C15 in the desired conguration.a. Label this stereogenic center as R or S.b. A well known synthesis of PGF2α involves reaction of A with Zn(BH4)2, a metal hydride reagent similar in reactivity to NaBH4, to form two isomeric products, B and C. Draw their structures and indicate their stereochemical relationship.c. Suggest a reagent to convert A to the single stereoisomer X.(a) How many Stereoisomers are possible for 9,10- dibromoexadecanoic acid?(b) Addition of bromine to palmitoleic acid primarily yields a set of enantiomers, (±) -three-9,10-dibromohexadecanoic acid. The addition of bromine is an anti-addition to the double bond (ie, it appears to occur through the intermediary of the bromonium ion). Taking into account the stereochemistry of the cis double bond of palmitoleic acid and the stereochemistry of adding bromine,Write a three-dimensional structure for (±) -three-9,10-dibromohexadecanoic acid!Friedel–Crafts alkylation of benzene with (R)-2-chlorobutane and AlCl3 affords sec-butylbenzene.a. How many stereogenic centers are present in the product?b. Would you expect the product to exhibit optical activity? Explain, with reference to the mechanism.
- Draw the products formed by the following acid-base reaction without consideration of the equilibrium position: You do not have to consider stereochemistry. You should include all products. Include counter-ions, e.g., Na+, I-, in your submission, but draw them in their own separate sketcher. Separate structures with + signs from the drop-down menu.1. Give the major organic product(s) of the reaction and include all the stereochemistry as appropriate. Identify any meso compounds. 2. Indicate whether a solution of the product would be optically active or no not active and provide a simple reasoning to support your choice. Need the last 2In some nucleophilic substitutions under SN1 conditions, complete racemization does not occur and a small excess of one enantiomer ispresent. For example, treatment of optically pure 1-bromo-1phenylpropane with water forms 1-phenylpropan-1-ol. (a) Calculate how much of each enantiomer is present using the given optical rotation data. (b) Which product predominates—the product of inversion or the product of retention of configuration? (c) Suggest an explanation for this phenomenon.