Question

Asked Jun 10, 2019

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This problem is (8.10) from a book "Thermodynamics and Statistical Mechanics An Integrated Approach by M. Scott Shell"

Step 1

For a system of variable composition (open system), the differential change in molar Gibbs free energy for 1 mol of a mixture/solution is written as:

Step 2

Applying Euler reciprocity relation to equation (4), we get,

Step 3

(b) Equation (5) is modified and rearranged as follows:

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