A 25.00cm3 of potassium dichromate(K2Cr2O7) solution are added to an acidified aqueous solution of potassium iodide(present in excess). The Iodine was then liberated according to the equation K2Cr2O7(aq) + 14H+(aq) + KI(aq) → K+(aq) + Cr3+(aq) + H2O(l) + I2(aq) required 19.63cm3 of a 0.1478MNa2S2O3 for complete reaction. The equation for the reaction of between Na2S2O3 and I2 is I2 +(aq) + Na2S2SO3(aq) → Na2S4O6(aq) + NaI(aq) Calculate the concentration of potassium dichromate (only 4 decimal places).    ________Mol/L

Principles of Modern Chemistry
8th Edition
ISBN:9781305079113
Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Chapter17: Electrochemistry
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A 25.00cm3 of potassium dichromate(K2Cr2O7) solution are added to an acidified aqueous solution of potassium iodide(present in excess). The Iodine was then liberated according to the equation

K2Cr2O7(aq) + 14H+(aq) + KI(aq) → K+(aq) + Cr3+(aq) + H2O(l) + I2(aq)

required 19.63cm3 of a 0.1478MNa2S2O3 for complete reaction. The equation for the reaction of between Na2S2O3 and I2 is

I+(aq) + Na2S2SO3(aq) → Na2S4O6(aq) + NaI(aq)

Calculate the concentration of potassium dichromate (only 4 decimal places).    ________Mol/L

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